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(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one

CAS号：753016-61-4

英文名：(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one

分子式

C48H86O6Si2

熔点

密度

分子量

815.364

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one

英文名称

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one

中文别名

英文别名

CAS号

753016-61-4

分子式

C48H86O6Si2

分子量

815.364

精确质量

814.596

PSA

85.22

LOGP

12.6859

合成路线

共找到2条合成路线 >

(E)-3-{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-2-methyl-acrylic acid ethyl ester

(E)-3-{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-2-methyl-acrylic acid ethyl ester

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one

上游原料

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{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-methanol

{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-methanol

(4R,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxane-5-carbaldehyde

(4R,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxane-5-carbaldehyde

Carbonic acid allyl ester (E)-(5S,6R,7R)-7-[(4S,5S)-5-((E)-3-bromo-2-methyl-propenyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-6-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-oct-2-enyl ester

Carbonic acid allyl ester (E)-(5S,6R,7R)-7-[(4S,5S)-5-((E)-3-bromo-2-methyl-propenyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-6-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-oct-2-enyl ester

(E)-(S)-6-Benzyloxy-2,4-dimethyl-hex-4-en-1-ol

(E)-(S)-6-Benzyloxy-2,4-dimethyl-hex-4-en-1-ol

(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-5-((E)-2-methyl-3-triisopropylsilanyloxy-propenyl)-[1,3]dioxane

(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-5-((E)-2-methyl-3-triisopropylsilanyloxy-propenyl)-[1,3]dioxane

(E)-(2S,4S,5R,6S)-10-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-5-hydroxy-2-(4-methoxy-benzyloxymethyl)-4,6,8-trimethyl-dec-8-en-3-one

(E)-(2S,4S,5R,6S)-10-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-5-hydroxy-2-(4-methoxy-benzyloxymethyl)-4,6,8-trimethyl-dec-8-en-3-one

下游产品

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(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenoic acid

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenoic acid

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenal

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenal

上游原料

{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-methanol (4R,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxane-5-carbaldehyde Carbonic acid allyl ester (E)-(5S,6R,7R)-7-[(4S,5S)-5-((E)-3-bromo-2-methyl-propenyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-6-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-oct-2-enyl ester (E)-(S)-6-Benzyloxy-2,4-dimethyl-hex-4-en-1-ol (4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-5-((E)-2-methyl-3-triisopropylsilanyloxy-propenyl)-[1,3]dioxane (E)-(2S,4S,5R,6S)-10-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-5-hydroxy-2-(4-methoxy-benzyloxymethyl)-4,6,8-trimethyl-dec-8-en-3-one (E)-3-{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-2-methyl-prop-2-en-1-ol (R)-4-Benzyl-3-((2R,3R)-4-benzyloxy-3-hydroxy-2-methyl-butyryl)-oxazolidin-2-one (E)-(S)-6-Benzyloxy-2,4-dimethyl-hex-4-enoic acid methyl ester (E)-(2S,3R,4S)-8-Benzyloxy-2-[(4S,5S)-5-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-4,6-dimethyl-oct-6-en-3-ol ((E)-(1R,2S)-6-Benzyloxy-1-{(R)-1-[(4S,5S)-5-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-ethyl}-2,4-dimethyl-hex-4-enyloxy)-tert-butyl-dimethyl-silane (E)-(2R,3S,4S,5R,6S)-10-Benzyloxy-2-(4-methoxy-benzyloxymethyl)-4,6,8-trimethyl-dec-8-ene-1,3,5-triol (E)-(5S,6R,7R)-6-(tert-Butyl-dimethyl-silanyloxy)-7-[(4S,5S)-2,2-dimethyl-5-((E)-2-methyl-3-triisopropylsilanyloxy-propenyl)-[1,3]dioxan-4-yl]-3,5-dimethyl-oct-2-en-1-ol (E)-(2S,3S,4S,5R,6S)-10-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-4,6,8-trimethyl-dec-8-ene-3,5-diol carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-19-(6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester (E)-(S)-6-Benzyloxy-2,4-dimethyl-hex-4-enal (2R)-2-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]propanal (E)-3-{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-2-methyl-acrylic acid ethyl ester carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-8-hydroxy-9-hydroxymethyl-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-nonadeca-2,10,12,16,18-pentaenyl ester carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-7-{5-[8-ethyl-10-(6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-2,6-dimethyl-deca-1,3,7,9-tetraenyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-3,5-dimethyl-oct-2-enyl ester carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-8-hydroxy-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester (2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol (5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-5-methyl-5,6-dihydro-2H-pyran-2-ol (5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-5-methyl-5,6-dihydro-pyran-2-one tert-Butyl-((2R,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-ylmethoxy)-diphenyl-silane (Z)-(S)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-pent-2-enoic acid methyl ester Carbonic acid allyl ester (E)-(5S,6R,7R)-6-(tert-butyl-dimethyl-silanyloxy)-7-[(4S,5S)-5-((E)-3-hydroxy-2-methyl-propenyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-3,5-dimethyl-oct-2-enyl ester (4Z,6E)-(R)-5-Ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dienal tert-Butyl-[(4Z,6E)-(R)-5-ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dienyloxy]-diphenyl-silane carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester Carbonic acid allyl ester (E)-(5S,6R,7R)-6-(tert-butyl-dimethyl-silanyloxy)-7-[(4S,5S)-2,2-dimethyl-5-((E)-2-methyl-3-triisopropylsilanyloxy-propenyl)-[1,3]dioxan-4-yl]-3,5-dimethyl-oct-2-enyl ester (4Z,6E)-(R)-5-Ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dien-1-ol (S)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-pent-2-ynoic acid methyl ester (R)-4-((S)-3,3-Dibromo-1-methyl-allyl)-2,2-dimethyl-[1,3]dioxolane

下游产品

(2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenoic acid (2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenal