化合物简介
Alpine borane is the commercial name for an organoboron compound that is used in organic synthesis. This reagent is generated by treating 9-BBN with α-pinene to give a sterically crowded trialkylborane. The resulting chiral species can stereoselectively reduce ketones, aldehydes, even deutero aldehydes in what is known as the Midland Alpine Borane Reduction, or simply the Midland Reduction:
基本信息
中文名称
R-Alpine-硼烷
英文名称
9-[(1R,3R,4S,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]-9-borabicyclo[3.3.1]nonane
中文别名
英文别名
B-Isopinocampheyl-9-borabicyclo[3.3.1]nonane solution、Alpine-borane、(R)-Alpine-Borane.(R)、B-Isopinocampheyl-9-borabicyclo[3.3.1]nonane、R-alpine borane
CAS号
73624-47-2
分子式
C18H31B
分子量
258.25
精确质量
258.252
PSA
0.0
LOGP
5.6617
编号系统
MDL号
MFCD00074776
PubChem号
24866131
物化性质
密度
0.896
沸点
>55ºC(lit.)
闪点
-17ºC
折射率
1.495
安全信息
安全说明
S16; S26; S27; S36/37/39; S24; S6
危险类别码
R11; R19; R22; R36/37/38
危险品运输编码
UN 1993
危险类别
4.3
包装等级
III
危险品标志
F; Xn