化合物简介
N-Methylmorpholine N-oxide (more correctly 4-methylmorpholine 4-oxide), NMO or NMMO is an organic compound. This heterocyclic amine oxide and morpholine derivative is used in organic chemistry as a co-oxidant and sacrificial catalyst in oxidation reactions for instance in osmium tetroxide oxidations and the Sharpless asymmetric dihydroxylation or oxidations with TPAP. NMO is commercially supplied both as a monohydrate C5H11NO2·H2O and as the anhydrous compound. The monohydrate is used as a solvent for cellulose in the Lyocell process to produce cellulose fibers.
基本信息
中文名称
N-甲基吗啉氮氧化物
英文名称
N-methylmorpholine N-oxide
中文别名
4-甲基吗啉-N-氧化物、N-甲基氧化吗啉、N-甲基吗啉-N-氧化物、4-甲基吗啡-N-氧化物、N-甲基吗啉氧化物
英文别名
4-Methylmorpholine N-Oxide、4-Methylmorpholine 4-oxide
CAS号
7529-22-8
分子式
C5H11NO2
分子量
117.146
精确质量
117.079
PSA
38.66
LOGP
-0.0802
编号系统
MDL号
MFCD00005947
物化性质
外观与性状
无色至略黄色透明液体
密度
1.14 g/cm3
沸点
118-119ºC
熔点
180-184ºC
闪点
118-119ºC
折射率
n20/D 1.43
稳定性
Stable at room temperature in closed containers under normal storage and handling conditions.
储存条件
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4ºC). Store protected from moisture.
安全信息
安全说明
S26-S36/37
危险类别码
R36/37/38
WGK Germany
1
海关编码
2934999090
危险品标志
Xi
危险性描述
H315; H319; H335
信号词
Warning
危险性防范说明
P261; P305 + P351 + P338
危险标志
GHS07