百科

(4Z,6E)-(R)-5-Ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dien-1-ol

(4Z,6E)-(R)-5-Ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dien-1-ol

CAS号：753016-75-0

英文名：(4Z,6E)-(R)-5-Ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dien-1-ol

分子式：C19H32O3

分子量：308.456

合成路线

tert-Butyl-[(4Z,6E)-(R)-5-ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dienyloxy]-diphenyl-silane

tert-Butyl-[(4Z,6E)-(R)-5-ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dienyloxy]-diphenyl-silane

(4Z,6E)-(R)-5-Ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dien-1-ol

(4Z,6E)-(R)-5-Ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dien-1-ol

上游原料

tert-Butyl-[(4Z,6E)-(R)-5-ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dienyloxy]-diphenyl-silane

下游产品

carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-8-hydroxy-9-hydroxymethyl-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-nonadeca-2,10,12,16,18-pentaenyl ester carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-7-{5-[8-ethyl-10-(6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-2,6-dimethyl-deca-1,3,7,9-tetraenyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-3,5-dimethyl-oct-2-enyl ester (2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-19-(6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-8-hydroxy-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester (2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenoic acid (2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenal carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester