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苯基1-硫代吡喃己糖苷

苯基1-硫代吡喃己糖苷

CAS号：77481-62-0

英文名：(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-phenylsulfanyloxane-3,4,5-triol

分子式

C12H16O5S

熔点

128 - 129 °C (乙醇)

密度

分子量

272.317

沸点

溶解度

信号词

危险品标志

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化合物简介

Phenyl 1-Thio-α-D-mannopyranoside is a reagent in the synthesis of phenyl 4,6-O-benzylidene-1-thio-α-D-mannopyranoside by using benzylidene acetal-directed β-mannosylation.

基本信息

中文名称

苯基1-硫代吡喃己糖苷

英文名称

(2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-phenylsulfanyloxane-3,4,5-triol

中文别名

英文别名

Phenyl a-D-thiomannopyranoside、Phenyl1-thio-a-D-mannopyranoside

CAS号

77481-62-0

分子式

C12H16O5S

分子量

272.317

精确质量

272.072

PSA

115.45

LOGP

-0.4214

物化性质

熔点

128 - 129 °C (乙醇)

合成路线

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2,3,4,6-O-四乙酰基-D-吡喃甘露糖

2,3,4,6-O-四乙酰基-D-吡喃甘露糖

苯基1-硫代吡喃己糖苷

苯基1-硫代吡喃己糖苷

上游原料

共找到2个上游原料 >

2,3,4,6-O-四乙酰基-D-吡喃甘露糖

2,3,4,6-O-四乙酰基-D-吡喃甘露糖

下游产品

共找到83个下游商品 >

phenyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside

phenyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside

tert-Butyl-diphenyl-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethoxy)-silane

tert-Butyl-diphenyl-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethoxy)-silane

phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-2-carbonylbenzoyl]-1-thio-α-D-mannopyranoside

phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-2-carbonylbenzoyl]-1-thio-α-D-mannopyranoside

benzyl O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-phthalate

benzyl O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-phthalate

(2S,3S,4aR,5R,7S,8S,8aS)-8-Benzyloxy-5-benzyloxymethyl-2,3-dimethoxy-2,3,7-trimethyl-hexahydro-pyrano[3,4-b][1,4]dioxin-7-ol

(2S,3S,4aR,5R,7S,8S,8aS)-8-Benzyloxy-5-benzyloxymethyl-2,3-dimethoxy-2,3,7-trimethyl-hexahydro-pyrano[3,4-b][1,4]dioxin-7-ol

phenyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->3)-2-O-acetyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

phenyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->3)-2-O-acetyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

上游原料

2,3,4,6-O-四乙酰基-D-吡喃甘露糖

下游产品

phenyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside tert-Butyl-diphenyl-((2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethoxy)-silane phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-2-carbonylbenzoyl]-1-thio-α-D-mannopyranoside benzyl O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-phthalate (2S,3S,4aR,5R,7S,8S,8aS)-8-Benzyloxy-5-benzyloxymethyl-2,3-dimethoxy-2,3,7-trimethyl-hexahydro-pyrano[3,4-b][1,4]dioxin-7-ol phenyl (2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->3)-2-O-acetyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside benzyl O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-oxalate phenyl O-(3,4,6-tri-O-acetyl-α-D-mannopyranosyl)-(1-3)-2,4-di-O-benzyl-1-thio-α-D-mannopyranoside 2,6-di-O-benzyl-3,4-O-[(2S,3S)-2,3-dimethoxybutan-2,3-diyl]-D-mannolactone (2S,3S,4aR,5R,7S,8S,8aS)-8-Benzyloxy-5-benzyloxymethyl-2,3-dimethoxy-2,3-dimethyl-7-phenyl-hexahydro-pyrano[3,4-b][1,4]dioxin-7-ol phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-3-carbonylpropanoyl]-1-sulfoxy-α-D-mannopyranoside phenyl 2,3,4-tri-O-benzyl-6-O-(t-butyloxycarbonylethanoyl)-1-thio-α-D-mannopyranoside phenyl 2,3-di-O-benzyl-4,6-O-p-methoxybenzylidene-1-thio-α-D-mannopyranoside allyl (2,3,4-tri-O-benzyl-α-D-mannopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside Phenyl 2,3-O-isopropylidene-1-thio-α-D-rhamnopyranoside benzyl O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-malonate phenyl 2-O-acetyl-3-O-benzyl-4,6-O-isopropylidene-1-thio-α-D-mannopyranoside phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-oxalyl]-1-thio-α-D-mannopyranoside Succinic acid (2R,4aR,6S,7R,8S,8aR)-7-benzoyloxy-6-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester (2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester phenyl {O-(3,4,6 -tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl)-(1→2)-O-[(3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2 -trichloroethoxycarbonylamino)-β-D-glucopyranosyl)-(1→4)]}-3,6 -di -O-allyl-1-thio-α-D-mannopyranoside Phenyl 4-O-benzyl-2,3-O-isopropylidene-1-thio-α-D-rhamnopyranoside phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-carbonyl]-1-sulfoxy-α-D-mannopyranoside phenyl 2,4-di-O-benzyl-1-thio-α-D-mannopyranosidurono-6,3-lactone {O-(3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl)-(1→2)-O-[(3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl)-(1→4)]}-1,3,6-tri-O-acetyl-β-D-mannopyranose benzyl O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-phthalate phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-oxalyl]-1-sulfoxy-α-D-mannopyranoside phenyl 2-O-acetyl-4,6-O-banelidene-1-thio-α-D-mannopyranoside methyl (phenyl 3-O-acetyl-2,4-di-O-benzyl-1-thio-α-D-mannopyranoside)uronate benzyl O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-carbonate (2R,3R,4S,5S,6S)-2-(acetoxymethyl)-6-(((2R,3R,4S,5S,6R)-3,5-bis(benzyloxy)-6-(phenylthio)-4-(((2R,3S,4S,5R,6R)-3,4,5-triacetoxy-6-(acetoxymethyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate phenyl 2,3,4-tri-O-benzyl-6-O-trityl-1-thio-α-D-mannopyranoside phenyl 2,3,4-tri-O-benzyl-6-O-chlorooxalyl-1-thio-α-D-mannopyranoside Phenyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-benzyl-2-O-pivaloyl-α-D-mannopyranosyl)-1-thio-α-D-mannopyranoside methyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-4,6-O-(di-tert-butylsilylene)-β-D-mannopyranosyl)-α-D-glucopyranoside allyl [2,3,4-tri-O-benzyl-6-O-(tert-butyldimethylsilyl)-α-D-mannopyranosyl]-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside Phenyl 4-O-benzyl-1-thio-α-D-rhamnopyranoside phenyl 2,3,4,6-tetra-O,O,O,S-acetyl-1,6-dithio-α-D-mannopyranoside allyl (2,3,4-tri-O-benzyl-6-O-{[2-(benzyloxycarbonylamino)ethyl](2-cyanoethyl)phosphonato}-α-D-mannopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside phenyl 3-O-benzyl-4,6-O-isopropylidene-1-thio-α-D-mannopyranoside phenyl 2,3,4-tri-O-benzyl-6-O-(2-hydroxycarbonylbenzoyl)-1-thio-α-D-mannopyranoside phenyl 2,3,4-tri-O-benzyl-6-O-chlorocarbonyl-1-thio-α-D-mannopyranoside S-phenyl 2,6-di-O-benzyl-3,4-O-(butane-2',3'-diyl)-1-thia-α-D-mannopyranoside phenyl 2,3,4-tri-O-benzyl-6-O-(hydroxycarbonylethanoyl)-1-thio-α-D-mannopyranoside phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-carbonyl]-1-thio-α-D-mannopyranoside methyl D-glycero-α-D-manno-heptopyranoside 7-phosphate