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methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate
CAS号:804551-86-8
英文名:methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate
分子式:C21H40O7Si
分子量:432.624
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合成路线
804551-93-7
(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester
804551-86-8
methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate
804551-89-1
(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester
804551-86-8
methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate
1035621-05-6
methyl 2-((2S,4S,5S,6S)-4-((tert-butyldimethylsilyl)oxy)-2-methoxy-6-((2R,3R,E)-3-methoxy-5-phenylpent-4-en-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate
804551-86-8
methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate
上游原料
(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester
(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester
methyl 2-((2S,4S,5S,6S)-4-((tert-butyldimethylsilyl)oxy)-2-methoxy-6-((2R,3R,E)-3-methoxy-5-phenylpent-4-en-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate
下游产品
(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one