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(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one

(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one

CAS号:804551-99-3
英文名:(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one
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基本信息
上游原料
(1S,2R)-1-((E)-5-bromo-pent-3-en-1-ynyl)-2-chloro-cyclopropane (2R,4S,5S)-4-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-5-methyl-3,7-dioxa-bicyclo[4.1.0]heptane-2-carboxylic acid methyl ester 5-[(4E,6E)-(1S,3R)-9-((1S,2R)-2-chloro-cyclopropyl)-1-methyl-3-trityloxy-nona-4,6-dien-8-ynylsulfanyl]-1-phenyl-1H-tetrazole (5S,6S)-7-benzyloxy-6-methoxy-5-methyl-hept-3-enoic acid methyl ester methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate 5-[(5E,7E)-(2R,4R)-10-((1S,2R)-2-Chloro-cyclopropyl)-4-(1-ethoxy-ethoxy)-deca-5,7-dien-9-yne-2-sulfonyl]-1-phenyl-1H-tetrazole (2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester (4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester (E)-5-((1S,2R)-2-chloro-cyclopropyl)-pent-2-en-4-yn-1-ol (5E,7E)-(2S,4R)-10-((1S,2R)-2-chloro-cyclopropyl)-4-trityloxy-deca-5,7-dien-9-yn-2-ol (2R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester (5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-5-methyl-4-oxo-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester [(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester 5-[(5E,7E)-(2S,4R)-10-((1S,2R)-2-chloro-cyclopropyl)-4-trityloxy-deca-5,7-dien-9-yne-2-sulfonyl]-1-phenyl-1H-tetrazole [(E)-5-((1S,2R)-2-chloro-cyclopropyl)-pent-2-en-4-ynyl]-phosphonic acid diethyl ester [(2S,4S,5S,6S)-6-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester (2R,3S)-4-benzyloxy-3-methoxy-2-methyl-butyraldehyde (4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone (1R,2S)-1-chloro-2-(2,2-dibromo-vinyl)-cyclopropane (5S,6S)-7-benzyloxy-6-hydroxy-5-methyl-hept-3-enoic acid methyl ester (4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-hydroxy-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester