百科

methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate

methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate

CAS号：804551-86-8

英文名：methyl 2-[6-((1S,2S)-2-methoxy-1-methyl-3-oxopropyl)-(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsilyloxy)perhydro-2H-pyran-2-yl]acetate

分子式：C21H40O7Si

分子量：432.624

上游原料

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester

(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

methyl 2-((2S,4S,5S,6S)-4-((tert-butyldimethylsilyl)oxy)-2-methoxy-6-((2R,3R,E)-3-methoxy-5-phenylpent-4-en-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

methyl 2-((2S,4S,5S,6S)-4-((tert-butyldimethylsilyl)oxy)-2-methoxy-6-((2R,3R,E)-3-methoxy-5-phenylpent-4-en-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

上游原料

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester (4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester methyl 2-((2S,4S,5S,6S)-4-((tert-butyldimethylsilyl)oxy)-2-methoxy-6-((2R,3R,E)-3-methoxy-5-phenylpent-4-en-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

下游产品

(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one