百科

(4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone

(4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone

CAS号：804552-06-5

英文名：(4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone

分子式：C26H40N2O5Si

分子量：488.692

合成路线

(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

(4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone

(4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester

(4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone

(4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone

上游原料

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester (4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

下游产品

(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one