百科

[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester

[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester

CAS号：804552-08-7

英文名：[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester

分子式：C21H42O7Si

分子量：434.639

合成路线

(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

(4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester

[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester

[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester

[(2S,4S,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((1S,2S)-3-hydroxy-2-methoxy-1-methyl-propyl)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester

上游原料

(2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester (4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester

下游产品

(E)-(5R,9R,10R,11S,12S,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-5-[(1E,3E)-6-((1S,2R)-2-chloro-cyclopropyl)-hexa-1,3-dien-5-ynyl]-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadeca-1(14),7-dien-3-one