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(11E,13E)-(4R,5S,6S,7R,9R,15R,16R)-15-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-7-[1,3]dioxolan-2-ylmethyl-16-ethyl-4,6-dihydroxy-5,9,13-trimethyl-oxacyclohexadeca-11,13-diene-2,10-dione

(11E,13E)-(4R,5S,6S,7R,9R,15R,16R)-15-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-7-[1,3]dioxolan-2-ylmethyl-16-ethyl-4,6-dihydroxy-5,9,13-trimethyl-oxacyclohexadeca-11,13-diene-2,10-dione

CAS号：80879-08-9

英文名：(11E,13E)-(4R,5S,6S,7R,9R,15R,16R)-15-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-7-[1,3]dioxolan-2-ylmethyl-16-ethyl-4,6-dihydroxy-5,9,13-trimethyl-oxacyclohexadeca-11,13-diene-2,10-dione

分子式

C39H68O12Si

熔点

密度

分子量

757.036

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(11E,13E)-(4R,5S,6S,7R,9R,15R,16R)-15-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-7-[1,3]dioxolan-2-ylmethyl-16-ethyl-4,6-dihydroxy-5,9,13-trimethyl-oxacyclohexadeca-11,13-diene-2,10-dione

英文名称

(11E,13E)-(4R,5S,6S,7R,9R,15R,16R)-15-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-7-[1,3]dioxolan-2-ylmethyl-16-ethyl-4,6-dihydroxy-5,9,13-trimethyl-oxacyclohexadeca-11,13-diene-2,10-dione

中文别名

英文别名

CAS号

80879-08-9

分子式

C39H68O12Si

分子量

757.036

精确质量

756.448

PSA

148.44

LOGP

5.3448

合成路线

(E)-(4R,5R)-4-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-5-hydroxy-2-methyl-hept-2-enal

(E)-(4R,5R)-4-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-5-hydroxy-2-methyl-hept-2-enal

(11E,13E)-(4R,5S,6S,7R,9R,15R,16R)-15-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-7-[1,3]dioxolan-2-ylmethyl-16-ethyl-4,6-dihydroxy-5,9,13-trimethyl-oxacyclohexadeca-11,13-diene-2,10-dione

(11E,13E)-(4R,5S,6S,7R,9R,15R,16R)-15-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-7-[1,3]dioxolan-2-ylmethyl-16-ethyl-4,6-dihydroxy-5,9,13-trimethyl-oxacyclohexadeca-11,13-diene-2,10-dione

上游原料

共找到8个上游原料 >

(E)-(4R,5R)-5-Acetoxy-4-[(2R,3R,4S,5R,6R)-5-(tert-butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-2-methyl-hept-2-enoic acid ethyl ester

(E)-(4R,5R)-5-Acetoxy-4-[(2R,3R,4S,5R,6R)-5-(tert-butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-2-methyl-hept-2-enoic acid ethyl ester

O-mycinosyltylonolide

O-mycinosyltylonolide

(E)-(4R,5R)-4-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-5-hydroxy-2-methyl-hept-2-enal

(E)-(4R,5R)-4-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-5-hydroxy-2-methyl-hept-2-enal

(3aR,5R,7E,9E,11R,12R,16R,17S,17aS)-12-ethyl-16-hydroxy-11-((((2R,3R,4R,5R,6R)-5-hydroxy-3,4-dimethoxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)methyl)-5,9,17-trimethyl-3,3a,11,12,15,16,17,17a-octahydro-4H-furo[2,3-f][1]oxacyclohexadecine-2,6,14(5H)-trione

(3aR,5R,7E,9E,11R,12R,16R,17S,17aS)-12-ethyl-16-hydroxy-11-((((2R,3R,4R,5R,6R)-5-hydroxy-3,4-dimethoxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)methyl)-5,9,17-trimethyl-3,3a,11,12,15,16,17,17a-octahydro-4H-furo[2,3-f][1]oxacyclohexadecine-2,6,14(5H)-trione

tert-Butyl-((2R,3R,4S,5R)-4,5-dimethoxy-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane

tert-Butyl-((2R,3R,4S,5R)-4,5-dimethoxy-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane

(E)-(4R,5R)-5-Acetoxy-4-hydroxymethyl-2-methyl-hept-2-enoic acid ethyl ester

(E)-(4R,5R)-5-Acetoxy-4-hydroxymethyl-2-methyl-hept-2-enoic acid ethyl ester

上游原料

(E)-(4R,5R)-5-Acetoxy-4-[(2R,3R,4S,5R,6R)-5-(tert-butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-2-methyl-hept-2-enoic acid ethyl ester O-mycinosyltylonolide (E)-(4R,5R)-4-[(2R,3R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-tetrahydro-pyran-2-yloxymethyl]-5-hydroxy-2-methyl-hept-2-enal (3aR,5R,7E,9E,11R,12R,16R,17S,17aS)-12-ethyl-16-hydroxy-11-((((2R,3R,4R,5R,6R)-5-hydroxy-3,4-dimethoxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)methyl)-5,9,17-trimethyl-3,3a,11,12,15,16,17,17a-octahydro-4H-furo[2,3-f][1]oxacyclohexadecine-2,6,14(5H)-trione tert-Butyl-((2R,3R,4S,5R)-4,5-dimethoxy-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane (E)-(4R,5R)-5-Acetoxy-4-hydroxymethyl-2-methyl-hept-2-enoic acid ethyl ester