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(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

CAS号：842125-13-7

英文名：(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

分子式：C24H40O4Si

分子量：420.658

合成路线

(2S,3R,E)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-3-hydroxy-6-((4-methoxybenzyl)oxy)-2-methylhex-4-en-1-one

(2S,3R,E)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-3-hydroxy-6-((4-methoxybenzyl)oxy)-2-methylhex-4-en-1-one

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

(2S,3R,E)-3-((tert-butyldimethylsilyl)oxy)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-6-((4-methoxybenzyl)oxy)-2-methylhex-4-en-1-one

(2S,3R,E)-3-((tert-butyldimethylsilyl)oxy)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-6-((4-methoxybenzyl)oxy)-2-methylhex-4-en-1-one

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

上游原料

(2S,3R,E)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-3-hydroxy-6-((4-methoxybenzyl)oxy)-2-methylhex-4-en-1-one (2S,3R,E)-3-((tert-butyldimethylsilyl)oxy)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-6-((4-methoxybenzyl)oxy)-2-methylhex-4-en-1-one

下游产品

7-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-7-{3-[1,12,14-tris-(tert-butyl-dimethyl-silanyloxy)-16-methoxy-6-methoxymethoxy-7,13,15-trimethyl-heptadeca-3,9-dienyl]-oxiranyl}-hepta-2,4-dienoic acid ethyl ester 7-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-7-{3-[1,12,14-tris-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-16-methoxy-7,13,15-trimethyl-heptadeca-3,9-dienyl]-oxiranyl}-hepta-2,4-dienoic acid ethyl ester (2E,4E)-(6R,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-7-{(2R,3R)-3-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-3,4-dihydroxy-butyl]-oxiranyl}-2,4,6-trimethyl-hepta-2,4-dienoic acid ethyl ester 7-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-7-{3-[1,12,14-tris-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-16-methoxy-7,13,15-trimethyl-heptadeca-3,9-dienyl]-oxiranyl}-hepta-2,4-dienoic acid ethyl ester (1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S,E)-6-((4S,5R,6S)-6-((2R,3S)-3-methoxybutan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)hex-4-en-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one (2E,4E)-(6R,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-7-{(2R,3R)-3-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-3-oxo-propyl]-oxiranyl}-2,4,6-trimethyl-hepta-2,4-dienoic acid ethyl ester 7-[6,8-bis-(tert-butyl-dimethyl-silanyloxy)-10-methoxy-1,7,9-trimethyl-undec-3-enyl]-2,15-bis-(tert-butyl-dimethyl-silanyloxy)-10,12,14-trimethyl-8,17-dioxa-bicyclo[14.1.0]heptadeca-4,10,12-trien-9-one (1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S)-4-hydroxybutan-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one 7-[6,8-bis-(tert-butyl-dimethyl-silanyloxy)-10-methoxy-1,7,9-trimethyl-undec-3-enyl]-2,15-bis-(tert-butyl-dimethyl-silanyloxy)-10,12,14-trimethyl-8,17-dioxa-bicyclo[14.1.0]heptadeca-4,10,12-trien-9-one