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(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S)-4-hydroxybutan-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S)-4-hydroxybutan-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

CAS号：882491-93-2

英文名：(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S)-4-hydroxybutan-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

分子式

C34H62O6Si2

熔点

密度

分子量

623.023

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S)-4-hydroxybutan-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

英文名称

(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S)-4-hydroxybutan-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

中文别名

英文别名

(4E,10E,12E)-(1R,2R,7S,14R,15S,16R)-2,15-Bis-(tert-butyl-dimethyl-silanyloxy)-7-((S)-3-hydroxy-1-methyl-propyl)-10,12,14-trimethyl-8,17-dioxa-bicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

CAS号

882491-93-2

分子式

C34H62O6Si2

分子量

623.023

精确质量

622.408

PSA

77.52

LOGP

8.3436

合成路线

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3R)-3-((R)-1-(tert-butyldimethylsilyloxy)but-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3R)-3-((R)-1-(tert-butyldimethylsilyloxy)but-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S)-4-hydroxybutan-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

(1R,2R,4E,7S,10E,12E,14R,15S,16R)-2,15-bis(tert-butyldimethylsilyloxy)-7-((S)-4-hydroxybutan-2-yl)-10,12,14-trimethyl-8,17-dioxabicyclo[14.1.0]heptadeca-4,10,12-trien-9-one

上游原料

共找到8个上游原料 >

(2E,4E)-(6R,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-7-((2R,3R)-3-formyl-oxiranyl)-2,4,6-trimethyl-hepta-2,4-dienoic acid ethyl ester

(2E,4E)-(6R,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-7-((2R,3R)-3-formyl-oxiranyl)-2,4,6-trimethyl-hepta-2,4-dienoic acid ethyl ester

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-(hydroxymethyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-(hydroxymethyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-hydroxy-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester

(6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-hydroxy-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester

(4R,5R,2E,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dienoic acid ethyl ester

(4R,5R,2E,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dienoic acid ethyl ester

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

(2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3R)-3-((R)-1-(tert-butyldimethylsilyloxy)but-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

(2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3R)-3-((R)-1-(tert-butyldimethylsilyloxy)but-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate

上游原料

(2E,4E)-(6R,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-7-((2R,3R)-3-formyl-oxiranyl)-2,4,6-trimethyl-hepta-2,4-dienoic acid ethyl ester (2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-(hydroxymethyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate (6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-hydroxy-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester (4R,5R,2E,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dienoic acid ethyl ester (2E,4R,5R,6E)-5-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)-2,4-dimethylocta-2,6-dien-1-ol (2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3R)-3-((R)-1-(tert-butyldimethylsilyloxy)but-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate (6R,7R,2E,4E,8E)-7-(tert-butyldimethylsilyloxy)-10-(4-methoxybenzyloxy)-2,4,6-trimethyldeca-2,4,8-trienoic acid ethyl ester (2E,4E,6R,7S)-ethyl 7-(tert-butyldimethylsilyloxy)-7-((2R,3S)-3-((R)-1-hydroxybut-3-enyl)oxiran-2-yl)-2,4,6-trimethylhepta-2,4-dienoate