百科

(1S,2S,4S,5R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2,5-diol

(1S,2S,4S,5R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2,5-diol

CAS号：852546-69-1

英文名：(1S,2S,4S,5R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2,5-diol

分子式

C33H46O6Si

熔点

密度

分子量

566.8

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1S,2S,4S,5R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2,5-diol

英文名称

(1S,2S,4S,5R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2,5-diol

中文别名

英文别名

CAS号

852546-69-1

分子式

C33H46O6Si

分子量

566.8

精确质量

566.306

PSA

77.38

LOGP

4.827

合成路线

共找到2条合成路线 >

(Z)-methyl trans-4,5-(isopropylidenedioxy)-2-hexenoate

(Z)-methyl trans-4,5-(isopropylidenedioxy)-2-hexenoate

(1S,2S,4S,5R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2,5-diol

(1S,2S,4S,5R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2,5-diol

上游原料

共找到11个上游原料 >

(4S,5R)-2,2,5-trimethyl-1,3-dioxolane-4-carbaldehyde

(4S,5R)-2,2,5-trimethyl-1,3-dioxolane-4-carbaldehyde

(1S,4S,5R,6R,8R)-8-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxymethyl-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octan-2-one

(1S,4S,5R,6R,8R)-8-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxymethyl-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octan-2-one

2,2-Dimethyl-propionic acid (1S,2R,3R,4S,7R)-7-(tert-butyl-dimethyl-silanyloxy)-5-oxo-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-2-ylmethyl ester

2,2-Dimethyl-propionic acid (1S,2R,3R,4S,7R)-7-(tert-butyl-dimethyl-silanyloxy)-5-oxo-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-2-ylmethyl ester

2,2-Dimethyl-propionic acid (1S,2R,3R,4S,5S,7R)-7-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-2-ylmethyl ester

2,2-Dimethyl-propionic acid (1S,2R,3R,4S,5S,7R)-7-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-2-ylmethyl ester

(1S,2R,3S,4S,7R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-oxo-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester

(1S,2R,3S,4S,7R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-oxo-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester

acetic acid (1S,4R)-(-)-4-hydroxycyclohex-2-enyl ester

acetic acid (1S,4R)-(-)-4-hydroxycyclohex-2-enyl ester

下游产品

共找到2个下游商品 >

(1S,2S,4R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-5-en-2-ol

(1S,2S,4R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-5-en-2-ol

(1R,2R)-1-[(1S,2R,3R,4R,7S)-7-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-7-hydroxy-3-(4-methoxy-benzyloxymethyl)-bicyclo[2.2.2]oct-5-en-2-yl]-propane-1,2-diol

(1R,2R)-1-[(1S,2R,3R,4R,7S)-7-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-7-hydroxy-3-(4-methoxy-benzyloxymethyl)-bicyclo[2.2.2]oct-5-en-2-yl]-propane-1,2-diol

上游原料

(4S,5R)-2,2,5-trimethyl-1,3-dioxolane-4-carbaldehyde (1S,4S,5R,6R,8R)-8-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxymethyl-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octan-2-one 2,2-Dimethyl-propionic acid (1S,2R,3R,4S,7R)-7-(tert-butyl-dimethyl-silanyloxy)-5-oxo-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-2-ylmethyl ester 2,2-Dimethyl-propionic acid (1S,2R,3R,4S,5S,7R)-7-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-2-ylmethyl ester (1S,2R,3S,4S,7R)-7-(tert-Butyl-dimethyl-silanyloxy)-5-oxo-3-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octane-2-carboxylic acid methyl ester acetic acid (1S,4R)-(-)-4-hydroxycyclohex-2-enyl ester (1S,2S,4S,5R,6R,8R)-8-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxymethyl-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octan-2-ol cis-(1S,4R)-4-(tert-butyldimethylsilyloxy)cyclohex-2-enol (1S,2S,4S,5R,6R,8R)-8-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-2-(dimethyl-phenyl-silanyl)-vinyl]-5-(4-methoxy-benzyloxymethyl)-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octan-2-ol (Z)-methyl trans-4,5-(isopropylidenedioxy)-2-hexenoate (1S,4S,5R,6R,8R)-8-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxymethyl)-6-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]octan-2-one

下游产品

(1S,2S,4R,7R,8R)-2-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-8-(4-methoxy-benzyloxymethyl)-7-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-bicyclo[2.2.2]oct-5-en-2-ol (1R,2R)-1-[(1S,2R,3R,4R,7S)-7-[(E)-2-(Dimethyl-phenyl-silanyl)-vinyl]-7-hydroxy-3-(4-methoxy-benzyloxymethyl)-bicyclo[2.2.2]oct-5-en-2-yl]-propane-1,2-diol