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(S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dienal

(S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dienal

CAS号：860651-99-6

英文名：(S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dienal

分子式

C38H50O8

熔点

密度

分子量

634.799

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dienal

英文名称

(S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dienal

中文别名

英文别名

(2Z,6E)-(S)-8-{(2R,6R)-6-[(E)-(R)-4-Hydroxy-5-(4-methoxy-benzyloxy)-2-methyl-pent-1-enyl]-4-methylene-tetrahydro-pyran-2-yl}-5-(4-methoxy-benzyloxymethoxy)-3-methyl-octa-2,6-dienal

CAS号

860651-99-6

分子式

C38H50O8

分子量

634.799

精确质量

634.351

PSA

92.68

LOGP

7.0626

合成路线

共找到2条合成路线 >

{2-((4R,6S)-[(R,E)-4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-6-[(1E,4Z)-6-(tert-butyldiphenylsilanyloxy)-4-methylhexa-1,4-dienyl]-[1,3]dioxan-4-yl)}acetic acid butyl ester

{2-((4R,6S)-[(R,E)-4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-6-[(1E,4Z)-6-(tert-butyldiphenylsilanyloxy)-4-methylhexa-1,4-dienyl]-[1,3]dioxan-4-yl)}acetic acid butyl ester

(S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dienal

(S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dienal

上游原料

共找到14个上游原料 >

ethyl (2E,5R)-6-[(4-methoxyphenyl)methoxy]-3-methyl-5-(1,1,2,2-tetramethyl-1-silapropoxy)hex-2-enoate

ethyl (2E,5R)-6-[(4-methoxyphenyl)methoxy]-3-methyl-5-(1,1,2,2-tetramethyl-1-silapropoxy)hex-2-enoate

(2E,4S,6Z)-1-((2R,6R)-{6-(R,E)-[4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-4-methylenetetrahydropyran-2-yl})-8-(tert-butyldiphenylsilanyloxy)-6-methylocta-2,6-dien-4-ol

(2E,4S,6Z)-1-((2R,6R)-{6-(R,E)-[4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-4-methylenetetrahydropyran-2-yl})-8-(tert-butyldiphenylsilanyloxy)-6-methylocta-2,6-dien-4-ol

{2-((4R,6S)-[(R,E)-4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-6-[(1E,4Z)-6-(tert-butyldiphenylsilanyloxy)-4-methylhexa-1,4-dienyl]-[1,3]dioxan-4-yl)}acetic acid butyl ester

{2-((4R,6S)-[(R,E)-4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-6-[(1E,4Z)-6-(tert-butyldiphenylsilanyloxy)-4-methylhexa-1,4-dienyl]-[1,3]dioxan-4-yl)}acetic acid butyl ester

(3R,5S,6E,9Z)-11-(tert-butyldiphenylsilanyloxy)-3,5-dihydroxy-9-methylundeca-6,9-dienoic acid butyl ester

(3R,5S,6E,9Z)-11-(tert-butyldiphenylsilanyloxy)-3,5-dihydroxy-9-methylundeca-6,9-dienoic acid butyl ester

(2R,6S)-2-[(E)-(R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-2-methyl-pent-1-enyl]-6-[(3E,6Z)-(S)-8-(tert-butyl-diphenyl-silanyloxy)-6-methyl-2-phenylselanyl-octa-3,6-dienyl]-4-methylene-tetrahydro-pyran

(2R,6S)-2-[(E)-(R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-2-methyl-pent-1-enyl]-6-[(3E,6Z)-(S)-8-(tert-butyl-diphenyl-silanyloxy)-6-methyl-2-phenylselanyl-octa-3,6-dienyl]-4-methylene-tetrahydro-pyran

(2S,3E,6Z)-1-((2S,6R)-{6-(R,E)-[4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-4-methylenetetrahydropyran-2-yl})-8-(tert-butyldiphenylsilanyloxy)-6-methylocta-3,6-dien-2-ol

(2S,3E,6Z)-1-((2S,6R)-{6-(R,E)-[4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-4-methylenetetrahydropyran-2-yl})-8-(tert-butyldiphenylsilanyloxy)-6-methylocta-3,6-dien-2-ol

下游产品

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(1R,2E,5R,8E,10Z,13S,14E,17R)-13-((4-methoxybenzyloxy)methoxy)-5-((4-methoxybenzyloxy)methyl)-3,11-dimethyl-19-methylene-6,21-dioxabicyclo[15.3.1]henicosa-2,8,10,14-tetraen-7-one

(1R,2E,5R,8E,10Z,13S,14E,17R)-13-((4-methoxybenzyloxy)methoxy)-5-((4-methoxybenzyloxy)methyl)-3,11-dimethyl-19-methylene-6,21-dioxabicyclo[15.3.1]henicosa-2,8,10,14-tetraen-7-one

(1R,2E,5R,8E,10Z,14E,17R)-5-(hydroxymethyl)-3,11-dimethyl-19-methylene-6,21-dioxabicyclo[15.3.1]henicosa-2,8,10,14-tetraene-7,13-dione

(1R,2E,5R,8E,10Z,14E,17R)-5-(hydroxymethyl)-3,11-dimethyl-19-methylene-6,21-dioxabicyclo[15.3.1]henicosa-2,8,10,14-tetraene-7,13-dione

上游原料

ethyl (2E,5R)-6-[(4-methoxyphenyl)methoxy]-3-methyl-5-(1,1,2,2-tetramethyl-1-silapropoxy)hex-2-enoate (2E,4S,6Z)-1-((2R,6R)-{6-(R,E)-[4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-4-methylenetetrahydropyran-2-yl})-8-(tert-butyldiphenylsilanyloxy)-6-methylocta-2,6-dien-4-ol {2-((4R,6S)-[(R,E)-4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-6-[(1E,4Z)-6-(tert-butyldiphenylsilanyloxy)-4-methylhexa-1,4-dienyl]-[1,3]dioxan-4-yl)}acetic acid butyl ester (3R,5S,6E,9Z)-11-(tert-butyldiphenylsilanyloxy)-3,5-dihydroxy-9-methylundeca-6,9-dienoic acid butyl ester (2R,6S)-2-[(E)-(R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-2-methyl-pent-1-enyl]-6-[(3E,6Z)-(S)-8-(tert-butyl-diphenyl-silanyloxy)-6-methyl-2-phenylselanyl-octa-3,6-dienyl]-4-methylene-tetrahydro-pyran (2S,3E,6Z)-1-((2S,6R)-{6-(R,E)-[4-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpent-1-enyl]-4-methylenetetrahydropyran-2-yl})-8-(tert-butyldiphenylsilanyloxy)-6-methylocta-3,6-dien-2-ol 1-<(trimethylsilyl)oxy>-1-ethoxy-3-methyl-1,3-butadiene (S,2Z,6E)-5-((4-methoxybenzyloxy)methoxy)-8-((2R,6R)-6-((R,E)-5-(4-methoxybenzyloxy)-4-hydroxy-2-methylpent-1-enyl)tetrahydro-4-methylene-2H-pyran-2-yl)-3-methylocta-2,6-dien-1-ol ethyl (2E)-(5R)-5-hydroxy-6-[(4-methoxyphenyl)-methoxy]-3-methylhex-2-enoate (S,6E,9Z)-11-(tert-butyldiphenylsilanyloxy)-5-hydroxy-9-methyl-3-oxoundeca-6,9-dienoic acid butyl ester (6E,9Z)-(3R,5S)-11-(tert-Butyl-diphenyl-silanyloxy)-9-methyl-3,5-bis-trimethylsilanyloxy-undeca-6,9-dienoic acid butyl ester (2E)(5R)-6-[(4-methoxyphenyl)methoxy]-3-methyl-5-(tert-butyldimethylsilyloxy)hex-2-enal 6-[(S,3E,6Z)-8-(tert-butyldiphenylsilanyloxy)-2-hydroxy-6-methylocta-3,6-dienyl]-2,2-dimethyl-[1,3]dioxin-4-one (2E,5Z)-7-(tert-butyldiphenylsilanyloxy)-5-methylhepta-2,5-dienal

下游产品

(1R,2E,5R,8E,10Z,13S,14E,17R)-13-((4-methoxybenzyloxy)methoxy)-5-((4-methoxybenzyloxy)methyl)-3,11-dimethyl-19-methylene-6,21-dioxabicyclo[15.3.1]henicosa-2,8,10,14-tetraen-7-one (1R,2E,5R,8E,10Z,14E,17R)-5-(hydroxymethyl)-3,11-dimethyl-19-methylene-6,21-dioxabicyclo[15.3.1]henicosa-2,8,10,14-tetraene-7,13-dione