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methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

CAS号：861113-87-3

英文名：methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

分子式

C42H60O11Si2

熔点

密度

分子量

797.09

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

英文名称

methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

中文别名

英文别名

CAS号

861113-87-3

分子式

C42H60O11Si2

分子量

797.09

精确质量

796.367

PSA

140.73

LOGP

6.5444

合成路线

共找到1条合成路线 >

(1S,4S,5R)-2-Methoxy-5-(4-methoxy-benzyloxy)-bicyclo[2.2.1]hept-2-ene

(1S,4S,5R)-2-Methoxy-5-(4-methoxy-benzyloxy)-bicyclo[2.2.1]hept-2-ene

methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

上游原料

共找到12个上游原料 >

(1S,4S,5R)-2-Methoxy-5-(4-methoxy-benzyloxy)-bicyclo[2.2.1]hept-2-ene

(1S,4S,5R)-2-Methoxy-5-(4-methoxy-benzyloxy)-bicyclo[2.2.1]hept-2-ene

(2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-10a-(methoxycarbonyl)-4-methyl-3,5-dioxodecahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-8,10-diyl diacetate

(2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-10a-(methoxycarbonyl)-4-methyl-3,5-dioxodecahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-8,10-diyl diacetate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-5-(hydroxymethyl)-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-5-(hydroxymethyl)-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-acetoxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-acetoxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

上游原料

(1S,4S,5R)-2-Methoxy-5-(4-methoxy-benzyloxy)-bicyclo[2.2.1]hept-2-ene (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-10a-(methoxycarbonyl)-4-methyl-3,5-dioxodecahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-8,10-diyl diacetate methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-5-(hydroxymethyl)-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-acetoxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate