百科

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

CAS号：861113-88-4

英文名：methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

分子式：C28H48O10Si2

分子量：600.846

合成路线

methyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-5-(hydroxymethyl)-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-5-(hydroxymethyl)-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-acetoxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-acetoxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

上游原料

methyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-5-(hydroxymethyl)-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3R,4R,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-acetoxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

下游产品

(2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-10a-(methoxycarbonyl)-4-methyl-3,5-dioxodecahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-8,10-diyl diacetate methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate