百科

(2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-10a-(methoxycarbonyl)-4-methyl-3,5-dioxodecahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-8,10-diyl diacetate

CAS号：861114-21-8

英文名：(2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-10a-(methoxycarbonyl)-4-methyl-3,5-dioxodecahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-8,10-diyl diacetate

分子式：C34H36O13

分子量：652.642

合成路线

615249-05-3

(1S,4S,5R)-2-Methoxy-5-(4-methoxy-benzyloxy)-bicyclo[2.2.1]hept-2-ene

861114-21-8

(2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-10a-(methoxycarbonyl)-4-methyl-3,5-dioxodecahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-8,10-diyl diacetate

861113-88-4

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

861114-21-8

861114-06-9

methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-acetoxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

861114-21-8

861114-12-7

861114-21-8

861114-02-5

methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

861114-21-8

861114-20-7

861114-21-8

861114-01-4

methyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-5-(hydroxymethyl)-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

861114-19-4

861114-11-6

861114-09-2

上游原料

(1S,4S,5R)-2-Methoxy-5-(4-methoxy-benzyloxy)-bicyclo[2.2.1]hept-2-ene methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-hydroxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3R,4S,4aR,5S,7aS,8S,10R,10aS)-3-acetoxy-4,5-dihydroxy-5-(hydroxymethyl)-4-methyl-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3R,4S,4aR,7aS,8S,10R,10aS)-3-acetoxy-4-hydroxy-4-methyl-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate methyl (2aR,2a1R,3S,4aS,7aS,8S,10R,10aS)-3-acetoxy-4-methylene-5-oxo-8,10-bis((2-(trimethylsilyl)ethoxy)methoxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate

下游产品

methyl (2aR,2a1R,4S,4aR,7aS,8S,10R,10aS)-4-((1S,2R,4S,6S)-6-(benzoyloxy)-3-oxobicyclo[2.2.1]heptan-2-yl)-4-methyl-3,5-dioxo-8,10-bis((triethylsilyl)oxy)octahydro-1H,7H-naphtho[1,8-bc:4,4a-c']difuran-10a(8H)-carboxylate