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(6S,9R,14aS,15R)-1,10-dihydroxy-9-(hydroxymethyl)-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

(6S,9R,14aS,15R)-1,10-dihydroxy-9-(hydroxymethyl)-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

CAS号：866110-95-4

英文名：(6S,9R,14aS,15R)-1,10-dihydroxy-9-(hydroxymethyl)-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

分子式

C27H34N2O8

熔点

密度

分子量

514.567

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(6S,9R,14aS,15R)-1,10-dihydroxy-9-(hydroxymethyl)-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

英文名称

(6S,9R,14aS,15R)-1,10-dihydroxy-9-(hydroxymethyl)-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

中文别名

英文别名

CAS号

866110-95-4

分子式

C27H34N2O8

分子量

514.567

精确质量

514.232

PSA

121.16

LOGP

2.0229

合成路线

866110-76-1

(6S,9R,14aS,15R)-1,10-dihydroxy-9-(hydroxymethyl)-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

(6S,9R,14aS,15R)-1,10-dihydroxy-9-(hydroxymethyl)-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

上游原料

共找到12个上游原料 >

{(S)-2-((1R,3S)-8-Allyloxy-1-allyloxymethyl-3-hydroxymethyl-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinolin-2-yl)-1-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-2-oxo-ethyl}-carbamic acid tert-butyl ester

{(S)-2-((1R,3S)-8-Allyloxy-1-allyloxymethyl-3-hydroxymethyl-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinolin-2-yl)-1-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-2-oxo-ethyl}-carbamic acid tert-butyl ester

{2-[8-allyloxy-1-allyloxymethyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinolin-2-yl]-1-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-2-oxo-ethyl}-carbamic acid tert-butyl ester

{2-[8-allyloxy-1-allyloxymethyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinolin-2-yl]-1-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-2-oxo-ethyl}-carbamic acid tert-butyl ester

(1R,3S)-8-Allyloxy-1-allyloxymethyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5,7-dimethoxy-6-methyl-1,2,3,4-tetrahydro-isoquinoline

(1R,3S)-8-Allyloxy-1-allyloxymethyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5,7-dimethoxy-6-methyl-1,2,3,4-tetrahydro-isoquinoline

(1R,3S,6R,11aS)-7-Allyloxy-6-allyloxymethyl-3-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-1-hydroxy-8,10-dimethoxy-9-methyl-4-oxo-1,3,4,6,11,11a-hexahydro-pyrazino[1,2-b]isoquinoline-2-carboxylic acid tert-butyl ester

(1R,3S,6R,11aS)-7-Allyloxy-6-allyloxymethyl-3-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-1-hydroxy-8,10-dimethoxy-9-methyl-4-oxo-1,3,4,6,11,11a-hexahydro-pyrazino[1,2-b]isoquinoline-2-carboxylic acid tert-butyl ester

(6S,9R,14aS,15R)-10-(allyloxy)-9-((allyloxy)methyl)-1-hydroxy-2,4,11,13-tetramethoxy-3,12-dimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

(6S,9R,14aS,15R)-10-(allyloxy)-9-((allyloxy)methyl)-1-hydroxy-2,4,11,13-tetramethoxy-3,12-dimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

(6S,9R,14aS,15R)-10-(allyloxy)-9-((allyloxy)methyl)-1-hydroxy-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

(6S,9R,14aS,15R)-10-(allyloxy)-9-((allyloxy)methyl)-1-hydroxy-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one

上游原料

{(S)-2-((1R,3S)-8-Allyloxy-1-allyloxymethyl-3-hydroxymethyl-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinolin-2-yl)-1-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-2-oxo-ethyl}-carbamic acid tert-butyl ester {2-[8-allyloxy-1-allyloxymethyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinolin-2-yl]-1-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-2-oxo-ethyl}-carbamic acid tert-butyl ester (1R,3S)-8-Allyloxy-1-allyloxymethyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5,7-dimethoxy-6-methyl-1,2,3,4-tetrahydro-isoquinoline (1R,3S,6R,11aS)-7-Allyloxy-6-allyloxymethyl-3-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-benzyl]-1-hydroxy-8,10-dimethoxy-9-methyl-4-oxo-1,3,4,6,11,11a-hexahydro-pyrazino[1,2-b]isoquinoline-2-carboxylic acid tert-butyl ester (6S,9R,14aS,15R)-10-(allyloxy)-9-((allyloxy)methyl)-1-hydroxy-2,4,11,13-tetramethoxy-3,12-dimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one (6S,9R,14aS,15R)-10-(allyloxy)-9-((allyloxy)methyl)-1-hydroxy-2,4,11,13-tetramethoxy-3,12,16-trimethyl-5,6,9,14,14a,15-hexahydro-7H-6,15-epiminobenzo[4,5]azocino[1,2-b]isoquinolin-7-one (1R,3S)-8-Allyloxy-1-allyloxymethyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinoline-2-carboxylic acid tert-butyl ester (1R,3S,6R,11aS)-7-Allyloxy-6-allyloxymethyl-1-hydroxy-3-(5-hydroxy-2,4-dimethoxy-3-methyl-benzyl)-8,10-dimethoxy-9-methyl-4-oxo-1,3,4,6,11,11a-hexahydro-pyrazino[1,2-b]isoquinoline-2-carboxylic acid tert-butyl ester (S)-1-[(1R,3S)-8-Allyloxy-1-allyloxymethyl-3-(tert-butyl-dimethyl-silanyloxymethyl)-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinolin-2-yl]-2-amino-3-[5-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-phenyl]-propan-1-one (1R,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-8-hydroxy-1-hydroxymethyl-5,7-dimethoxy-6-methyl-3,4-dihydro-1H-isoquinoline-2-carboxylic acid tert-butyl ester (S)-3-[5-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethoxy-3-methyl-phenyl]-2-(9H-fluoren-9-ylmethoxycarbonylamino)-propionic acid