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ethyl (2E,4R,6S,7S,10S,12E)-4-(tert-butyldimethylsilyloxy)-10-(tert-butyldiphenylsilyloxy)-7-hydroxy-6-((2-pyridylselenyl)methyl)tetradeca-2,12-dienoate

ethyl (2E,4R,6S,7S,10S,12E)-4-(tert-butyldimethylsilyloxy)-10-(tert-butyldiphenylsilyloxy)-7-hydroxy-6-((2-pyridylselenyl)methyl)tetradeca-2,12-dienoate

CAS号：866138-97-8

英文名：ethyl (2E,4R,6S,7S,10S,12E)-4-(tert-butyldimethylsilyloxy)-10-(tert-butyldiphenylsilyloxy)-7-hydroxy-6-((2-pyridylselenyl)methyl)tetradeca-2,12-dienoate

分子式

C44H65NO5SeSi2

熔点

密度

分子量

823.122

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

ethyl (2E,4R,6S,7S,10S,12E)-4-(tert-butyldimethylsilyloxy)-10-(tert-butyldiphenylsilyloxy)-7-hydroxy-6-((2-pyridylselenyl)methyl)tetradeca-2,12-dienoate

英文名称

ethyl (2E,4R,6S,7S,10S,12E)-4-(tert-butyldimethylsilyloxy)-10-(tert-butyldiphenylsilyloxy)-7-hydroxy-6-((2-pyridylselenyl)methyl)tetradeca-2,12-dienoate

中文别名

英文别名

(2E,12E)-(4R,6R,7S,10S)-4-(tert-Butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-7-hydroxy-6-(pyridin-2-ylselanylmethyl)-tetradeca-2,12-dienoic acid ethyl ester

CAS号

866138-97-8

分子式

C44H65NO5SeSi2

分子量

823.122

精确质量

823.357

PSA

77.88

LOGP

8.3979

合成路线

(R)-5-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-2-(tert-butyl-dimethyl-silanyloxy)-5-oxo-pentanal

(R)-5-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-2-(tert-butyl-dimethyl-silanyloxy)-5-oxo-pentanal

ethyl (2E,4R,6S,7S,10S,12E)-4-(tert-butyldimethylsilyloxy)-10-(tert-butyldiphenylsilyloxy)-7-hydroxy-6-((2-pyridylselenyl)methyl)tetradeca-2,12-dienoate

ethyl (2E,4R,6S,7S,10S,12E)-4-(tert-butyldimethylsilyloxy)-10-(tert-butyldiphenylsilyloxy)-7-hydroxy-6-((2-pyridylselenyl)methyl)tetradeca-2,12-dienoate

上游原料

共找到13个上游原料 >

(4S,6E)-1-tert-butyldimethylsilyloxy-4-tert-butyldiphenylsilyloxy-6-octene

(4S,6E)-1-tert-butyldimethylsilyloxy-4-tert-butyldiphenylsilyloxy-6-octene

(4S,6E)-4-(tert-butyldiphenylsilyloxy)oct-6-enal

(4S,6E)-4-(tert-butyldiphenylsilyloxy)oct-6-enal

(R)-5-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-2-(tert-butyl-dimethyl-silanyloxy)-5-oxo-pentanal

(R)-5-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-2-(tert-butyl-dimethyl-silanyloxy)-5-oxo-pentanal

(4S,6E)-4-tert-butyldiphenylsilyloxy-6-octen-1-ol

(4S,6E)-4-tert-butyldiphenylsilyloxy-6-octen-1-ol

(R)-4-benzyl-3-((R)-4-(tert-butyldimethylsilyloxy)-5-hydroxypentanoyl)oxazolidin-2-one

(R)-4-benzyl-3-((R)-4-(tert-butyldimethylsilyloxy)-5-hydroxypentanoyl)oxazolidin-2-one

(2S)-2,5-dihydroxy-1-tosyloxypentane

(2S)-2,5-dihydroxy-1-tosyloxypentane

上游原料

(4S,6E)-1-tert-butyldimethylsilyloxy-4-tert-butyldiphenylsilyloxy-6-octene (4S,6E)-4-(tert-butyldiphenylsilyloxy)oct-6-enal (R)-5-((R)-4-Benzyl-2-oxo-oxazolidin-3-yl)-2-(tert-butyl-dimethyl-silanyloxy)-5-oxo-pentanal (4S,6E)-4-tert-butyldiphenylsilyloxy-6-octen-1-ol (R)-4-benzyl-3-((R)-4-(tert-butyldimethylsilyloxy)-5-hydroxypentanoyl)oxazolidin-2-one (2S)-2,5-dihydroxy-1-tosyloxypentane (2S)-5-{[(tert-butyl)(dimethyl)silyl]oxy}-2-hydroxypentyl 4-methylbenzenesulfonate ethyl (2E,4R)-7-((R)-4-benzyl-2-oxo-1,3-oxazolidin-3-yl)-4-(tert-butyldimethylsilyloxy)-7-oxohept-2-enoate ethyl (2E,4R,6R,7S,10S,12E)-6-((R)-4-benzyl-2-oxo-1,3-oxazolidine-3-carbonyl)-4-(tert-butyldimethylsilyloxy)-10-(tert-butyldiphenylsilyloxy)-7-hydroxytetradeca-2,12-dienoate (R)-4-benzyl-3-((R)-4-(tert-butyldimethylsilyloxy)-5-(4-methoxybenzyloxy)pentanoyl)oxazolidin-2-one (R)-4-(tert-butyldimethylsilyloxy)-5-(4-methoxybenzyloxy)pentanoic acid (4S,6E)-1-(tert-butyldimethylsilyloxy)oct-6-en-4-ol (tert-butyl)(dimethyl){3-[(2S)-oxiran-2-yl]propoxy}silane