百科

2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S),4(R),4a(S),5,5a(S),6(S),11(R),11a(R),12,12a(S)-decahydronaphthacene

CAS号：86668-55-5

英文名：2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

分子式

C34H50O8Si

熔点

197 - 198 °C (甲苯)

密度

分子量

614.841

沸点

溶解度

信号词

危险品标志

若想填写更详细的询价信息，请点击进入询价页面

点我

基本信息

中文名称

2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

英文名称

2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

中文别名

英文别名

CAS号

86668-55-5

分子式

C34H50O8Si

分子量

614.841

精确质量

614.327

PSA

103.68

LOGP

6.189

物化性质

熔点

197 - 198 °C (甲苯)

合成路线

共找到9条合成路线 >

10-hydroxy-1-acetoxy-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene

10-hydroxy-1-acetoxy-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene

2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

上游原料

共找到14个上游原料 >

rac-(7R,7aR,8aR,9S,10S,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-9,10-dihydroxy-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one

rac-(7R,7aR,8aR,9S,10S,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-9,10-dihydroxy-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one

6-(tert-butyldimethylsiloxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-2-oxo-1,2,4a(R*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

6-(tert-butyldimethylsiloxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-2-oxo-1,2,4a(R*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-2-oxo-1,2,3(R*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-dodecahydronaphthacene

6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-2-oxo-1,2,3(R*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-dodecahydronaphthacene

1-hydroxy-10-(tert-butyldimethylsiloxy)-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene

1-hydroxy-10-(tert-butyldimethylsiloxy)-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene

2-acetyl-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

rac-(7R,7aR,8aS,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-10-((4-methoxyphenyl)sulfinyl)-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one

rac-(7R,7aR,8aS,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-10-((4-methoxyphenyl)sulfinyl)-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one

下游产品

共找到9个下游商品 >

12a-deoxypillaromycinone pentaacetate

12a-deoxypillaromycinone pentaacetate

2-acetyl-10-acetoxy-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-6-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10-acetoxy-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-6-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

Acetic acid (9R,10S,10aR)-4-acetoxy-6-(3-acetoxy-2,2-dimethyl-propoxy)-8-acetyl-9,10-dihydroxy-9,10,10a,11-tetrahydro-naphthacen-5-yl ester

Acetic acid (9R,10S,10aR)-4-acetoxy-6-(3-acetoxy-2,2-dimethyl-propoxy)-8-acetyl-9,10-dihydroxy-9,10,10a,11-tetrahydro-naphthacen-5-yl ester

2-acetyl-10-acetoxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10-acetoxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-10-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-10-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

上游原料

rac-(7R,7aR,8aR,9S,10S,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-9,10-dihydroxy-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one 6-(tert-butyldimethylsiloxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-2-oxo-1,2,4a(R*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene 6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-2-oxo-1,2,3(R*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-dodecahydronaphthacene 1-hydroxy-10-(tert-butyldimethylsiloxy)-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene 2-acetyl-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene rac-(7R,7aR,8aS,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-10-((4-methoxyphenyl)sulfinyl)-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one 1-acetoxy-8,9-(di-tert-butylsilylenedioxy)-10-oxo-1(R*),4,4a(S*),9(R*),9a(S*),10-hexahydroanthracene 10-(tert-butyldimethylsiloxy)-8,9-(di-tert-butylsilylenedioxy)-1-oxo-1,4,4a(S*),9(R*),9a(R*),10(S*)-hexahydroanthracene 1-acetoxy-10-(tert-butyldimethylsiloxy)-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene 10-hydroxy-1-acetoxy-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene 2-acetoxy-6-(tert-butyldimethylsiloxy)-10,11-(di-tert-butylsilylenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3-((4'-methoxyphenyl)thio)-1,4,4a(R*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

下游产品

12a-deoxypillaromycinone pentaacetate 2-acetyl-10-acetoxy-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-6-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene 2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene Acetic acid (9R,10S,10aR)-4-acetoxy-6-(3-acetoxy-2,2-dimethyl-propoxy)-8-acetyl-9,10-dihydroxy-9,10,10a,11-tetrahydro-naphthacen-5-yl ester 2-acetyl-10-acetoxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene 2-acetyl-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-10-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene