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2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S),4(R),4a(S*),5-tetrahydronaphthacene

CAS号：86668-61-3

英文名：2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

分子式：C34H38O10

分子量：606.66

合成路线

10-hydroxy-1-acetoxy-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene

10-hydroxy-1-acetoxy-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

rac-(7R,7aR,8aS,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-10-((4-methoxyphenyl)sulfinyl)-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one

rac-(7R,7aR,8aS,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-10-((4-methoxyphenyl)sulfinyl)-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

1-hydroxy-10-(tert-butyldimethylsiloxy)-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene

1-hydroxy-10-(tert-butyldimethylsiloxy)-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10-acetoxy-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-6-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10-acetoxy-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-6-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10-acetoxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10-acetoxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

2-acetyl-10,11-diacetoxy-3,4-(isopropylidenedioxy)-12-(3'-acetoxy-2',2'-dimethylpropan-1'-yloxy)-3(S*),4(R*),4a(S*),5-tetrahydronaphthacene

上游原料

10-hydroxy-1-acetoxy-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene 2-acetyl-10-acetoxy-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-6-hydroxy-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene 2-acetyl-10,11-dihydroxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11(R*),11a(R*),12,12a(S*)-decahydronaphthacene 1-hydroxy-10-(tert-butyldimethylsiloxy)-8,9-(di-tert-butylsilylenedioxy)-1(R*),4,4a(S*),9(R*),9a(S*),10(S*)-hexahydroanthracene 2-acetyl-10-acetoxy-6-(tert-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)-12,12-(2',2'-dimethylpropane-1',3'-diyldioxy)-11-oxo-3(S*),4(R*),4a(S*),5,5a(S*),6(S*),11a(R*),12,12a(S*)-decahydronaphthacene rac-(7R,7aR,8aS,12aR,13aS,13bS)-2,2-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-10-((4-methoxyphenyl)sulfinyl)-5',5'-dimethyl-7,7a,8,8a,9,10,12,12a,13a,13b-decahydro-11H-spiro[tetraceno[1,12-de][1,3,2]dioxasiline-13,2'-[1,3]dioxan]-11-one

下游产品

12a-deoxypillaromycinone pentaacetate Acetic acid (9R,10S,10aR)-4-acetoxy-6-(3-acetoxy-2,2-dimethyl-propoxy)-8-acetyl-9,10-dihydroxy-9,10,10a,11-tetrahydro-naphthacen-5-yl ester