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6-{1-acetoxy-2-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-ethyl}-5a-formyl-8-hydroxy-2,2-dimethyl-5-oxo-3a,4,5,5a,6,7,9a,9b-octahydro-naphtho[1,2-d][1,3]dioxole-9-carboxylic acid allyl ester

6-{1-acetoxy-2-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-ethyl}-5a-formyl-8-hydroxy-2,2-dimethyl-5-oxo-3a,4,5,5a,6,7,9a,9b-octahydro-naphtho[1,2-d][1,3]dioxole-9-carboxylic acid allyl ester

CAS号：872525-84-3

英文名：6-{1-acetoxy-2-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-ethyl}-5a-formyl-8-hydroxy-2,2-dimethyl-5-oxo-3a,4,5,5a,6,7,9a,9b-octahydro-naphtho[1,2-d][1,3]dioxole-9-carboxylic acid allyl ester

分子式

C45H56O11Si

熔点

57 - 59 °C

密度

分子量

801.005

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

6-{1-acetoxy-2-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-ethyl}-5a-formyl-8-hydroxy-2,2-dimethyl-5-oxo-3a,4,5,5a,6,7,9a,9b-octahydro-naphtho[1,2-d][1,3]dioxole-9-carboxylic acid allyl ester

英文名称

6-{1-acetoxy-2-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-ethyl}-5a-formyl-8-hydroxy-2,2-dimethyl-5-oxo-3a,4,5,5a,6,7,9a,9b-octahydro-naphtho[1,2-d][1,3]dioxole-9-carboxylic acid allyl ester

中文别名

英文别名

CAS号

872525-84-3

分子式

C45H56O11Si

分子量

801.005

精确质量

800.359

PSA

151.73

LOGP

5.7258

物化性质

熔点

57 - 59 °C

合成路线

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4-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-2-methylene-butane-1,3-diol

4-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-2-methylene-butane-1,3-diol

6-{1-acetoxy-2-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-ethyl}-5a-formyl-8-hydroxy-2,2-dimethyl-5-oxo-3a,4,5,5a,6,7,9a,9b-octahydro-naphtho[1,2-d][1,3]dioxole-9-carboxylic acid allyl ester

6-{1-acetoxy-2-[2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-ethyl}-5a-formyl-8-hydroxy-2,2-dimethyl-5-oxo-3a,4,5,5a,6,7,9a,9b-octahydro-naphtho[1,2-d][1,3]dioxole-9-carboxylic acid allyl ester

上游原料

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((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-acetaldehyde

((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-acetaldehyde

(3aR,7aS)-2,2-Dimethyl-6-oxo-3a,6,7,7a-tetrahydro-benzo[1,3]dioxole-5-carbaldehyde

(3aR,7aS)-2,2-Dimethyl-6-oxo-3a,6,7,7a-tetrahydro-benzo[1,3]dioxole-5-carbaldehyde

4-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-2-methylene-butane-1,3-diol

4-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-2-methylene-butane-1,3-diol

3,4-O-isopropylidene-2-deoxy-D-ribono-1,5-lactone

3,4-O-isopropylidene-2-deoxy-D-ribono-1,5-lactone

(E)-(R)-6-Acetoxy-7-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-3-oxo-hept-4-enoic acid allyl ester

(E)-(R)-6-Acetoxy-7-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-3-oxo-hept-4-enoic acid allyl ester

2-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide

2-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide

下游产品

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(3S,3aR,5R,5aS,5bS,9aS,10aS,13aR,13bS,15aR,15bS)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-15b-hydroxy-3a,8,8,12,12-pentamethyl-15-oxohexadecahydro-6H-cyclopenta[7,8][1,3]dioxolo[4',5':1,2]phenanthro[4,4a-d][1,3]dioxin-5-yl acetate

(3S,3aR,5R,5aS,5bS,9aS,10aS,13aR,13bS,15aR,15bS)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-15b-hydroxy-3a,8,8,12,12-pentamethyl-15-oxohexadecahydro-6H-cyclopenta[7,8][1,3]dioxolo[4',5':1,2]phenanthro[4,4a-d][1,3]dioxin-5-yl acetate

(R)-2-((1R,2S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-1-methyl-5-oxocyclopentyl)-1-((4S,4aR,8aS,9aS,12aR,12bS)-7,7,11,11-tetramethyl-2-oxooctahydro-2H,5H-[1,3]dioxolo[4',5':3,4]naphtho[1,8a-d][1,3]dioxin-4-yl)ethyl acetate

(R)-2-((1R,2S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-1-methyl-5-oxocyclopentyl)-1-((4S,4aR,8aS,9aS,12aR,12bS)-7,7,11,11-tetramethyl-2-oxooctahydro-2H,5H-[1,3]dioxolo[4',5':3,4]naphtho[1,8a-d][1,3]dioxin-4-yl)ethyl acetate

acetic acid 17-(tert-butyl-diphenyl-silanyloxymethyl)-4,14-dihydroxy-13-methyl-1,7-dioxo-10-(2-trimethylsilanyl-ethoxymethoxymethyl)-4,5,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-11-yl ester

acetic acid 17-(tert-butyl-diphenyl-silanyloxymethyl)-4,14-dihydroxy-13-methyl-1,7-dioxo-10-(2-trimethylsilanyl-ethoxymethoxymethyl)-4,5,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-11-yl ester

Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5S,5aR,6S,9aS,9bR)-5-hydroxy-5a-hydroxymethyl-2,2-dimethyl-8-oxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester

Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5S,5aR,6S,9aS,9bR)-5-hydroxy-5a-hydroxymethyl-2,2-dimethyl-8-oxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester

Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-[(3aS,5aR,6S,9aS,9bR)-2,2-dimethyl-5,8-dioxo-5a-(2-trimethylsilanyl-ethoxymethoxymethyl)-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl]-ethyl ester

Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-[(3aS,5aR,6S,9aS,9bR)-2,2-dimethyl-5,8-dioxo-5a-(2-trimethylsilanyl-ethoxymethoxymethyl)-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl]-ethyl ester

Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5aR,6S,9aS,9bR)-5a-hydroxymethyl-2,2-dimethyl-5,8-dioxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester

Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5aR,6S,9aS,9bR)-5a-hydroxymethyl-2,2-dimethyl-5,8-dioxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester

上游原料

((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-acetaldehyde (3aR,7aS)-2,2-Dimethyl-6-oxo-3a,6,7,7a-tetrahydro-benzo[1,3]dioxole-5-carbaldehyde 4-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-2-methylene-butane-1,3-diol 3,4-O-isopropylidene-2-deoxy-D-ribono-1,5-lactone (E)-(R)-6-Acetoxy-7-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-3-oxo-hept-4-enoic acid allyl ester 2-((4S,5R)-2,2-Dimethyl-5-vinyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide 2-((4S,5S)-5-Formyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide (3aS,7aR)-6-Hydroxymethyl-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-5-ol 2-((4S,5R)-5-Hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide

下游产品

(3S,3aR,5R,5aS,5bS,9aS,10aS,13aR,13bS,15aR,15bS)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-15b-hydroxy-3a,8,8,12,12-pentamethyl-15-oxohexadecahydro-6H-cyclopenta[7,8][1,3]dioxolo[4',5':1,2]phenanthro[4,4a-d][1,3]dioxin-5-yl acetate (R)-2-((1R,2S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-1-methyl-5-oxocyclopentyl)-1-((4S,4aR,8aS,9aS,12aR,12bS)-7,7,11,11-tetramethyl-2-oxooctahydro-2H,5H-[1,3]dioxolo[4',5':3,4]naphtho[1,8a-d][1,3]dioxin-4-yl)ethyl acetate acetic acid 17-(tert-butyl-diphenyl-silanyloxymethyl)-4,14-dihydroxy-13-methyl-1,7-dioxo-10-(2-trimethylsilanyl-ethoxymethoxymethyl)-4,5,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-11-yl ester Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5S,5aR,6S,9aS,9bR)-5-hydroxy-5a-hydroxymethyl-2,2-dimethyl-8-oxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-[(3aS,5aR,6S,9aS,9bR)-2,2-dimethyl-5,8-dioxo-5a-(2-trimethylsilanyl-ethoxymethoxymethyl)-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl]-ethyl ester Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5aR,6S,9aS,9bR)-5a-hydroxymethyl-2,2-dimethyl-5,8-dioxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester Acetic acid (R)-2-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-1-methyl-5-oxo-cyclopentyl]-1-((3aS,5aR,6S,9aS,9bR)-5a-formyl-2,2-dimethyl-5,8-dioxo-decahydro-naphtho[1,2-d][1,3]dioxol-6-yl)-ethyl ester (3S,3aR,5R,5aS,5bR,9aS,10aS,13aR,13bS,15aR,15bS)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-15b-hydroxy-3a,8,8,12,12-pentamethyl-15-oxo-14-(phenylselanyl)hexadecahydro-6H-cyclopenta[7,8][1,3]dioxolo[4',5':1,2]phenanthro[4,4a-d][1,3]dioxin-5-yl acetate