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(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
CAS号:890016-81-6
英文名:(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
分子式:C38H66O8Si
分子量:679.011
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合成路线
890016-95-2
(2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentanal
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
186489-79-2
(R)-4-Benzyl-3-[(R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionyl]-oxazolidin-2-one
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
890017-07-9
(R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propan-1-one
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
890016-92-9
(2S,3R)-2-((4R,5R,6R)-6-((S)-1-iodopropan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-3-ol
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
890016-99-6
(2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-methyl-3-(triisopropylsilyloxy)pentan-1-one
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
890016-84-9
(2R,3S,4R,5R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-2,4-dimethyl-5-(triisopropylsilyloxy)heptan-1-one
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
890017-00-2
(2R,3S,4S,5R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-(tert-butyldimethylsilyloxy)-2,4-dimethyl-5-(triisopropylsilyloxy)heptan-1-one
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
890017-02-4
(2R,3S,4S,5S,6S,7R)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-ol
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
890016-91-8
(2S,3R,4R,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-2,4,6-trimethyl-3-triethylsilanyloxy-7-triisopropylsilanyloxy-nonane
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
890016-86-1
(2S,3R,4S,5R,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-2,4,6-trimethyl-7-(triisopropylsilyloxy)nonan-1-one
890016-81-6
(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
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上游原料
(2R,3S,4S,5R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-(tert-butyldimethylsilyloxy)-2,4-dimethyl-5-(triisopropylsilyloxy)heptan-1-one
(4R)-4-benzyl-3-{(2R)-2-[(4S,5R,6R)-6-((1S,2R,3R)-3-{(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyldimethylsiloxy)-1-methylbutyl]-2-(p-methoxyphenyl)-5-methyl-m-dioxan-4-yl}-2-hydroxy-1-methylbutyl)-2,2,5-trimethyl-m-dioxan-4-yl]propionyl}-2-oxazolidinone.....
(2R,3S,4S,5S,6S,7R)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-ol
(2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-methyl-3-(triisopropylsilyloxy)pentan-1-one
(2S,3R,4R,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-2,4,6-trimethyl-3-triethylsilanyloxy-7-triisopropylsilanyloxy-nonane
(2S,3R,4S,5R,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-2,4,6-trimethyl-7-(triisopropylsilyloxy)nonan-1-one
(2R,3S,4S,6R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-6-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3-hydroxy-2,4-dimethyl-heptan-1-one
(2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentanal
(R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propan-1-one
(2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-2-methylpentan-1-one
(2S,3R,4R,5S,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-one
(R)-4-benzyl-3-((R)-2-((4S,5R,6S)-6-((2S,3R,4R)-4-((2R,4S,5S,6R)-6-((2R,3R)-3-((tert-butyldimethylsilyl)oxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxypentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoyl)oxazolidin-2-one
(2S,3R)-2-methyl-3-(triisopropylsilyloxy)pentanal
(2R,3S,4S,5S,6S,8R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-8-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3-hydroxy-2,4,6-trimethyl-5-triethylsilanyloxy-nonan-1-one
(R)-4-Benzyl-3-[(R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionyl]-oxazolidin-2-one
(2S,3R)-2-((4R,5R,6R)-6-((S)-1-iodopropan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-3-ol
(2R,3S,4R,5R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-2,4-dimethyl-5-(triisopropylsilyloxy)heptan-1-one
(2S,4R)-4-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-methyl-pentanoic acid ((1R,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide
(2R,3S,4R,5S,6S,8R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-8-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3,5-dihydroxy-2,4,6-trimethyl-nonan-1-one
(2R,3S,4S,5R)-3-(tert-butyldimethylsilyloxy)-2,4-dimethyl-5-(triisopropylsilyloxy)heptanal
(2R,3S,4S,6R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-6-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2,4-dimethyl-3-triethylsilanyloxy-heptan-1-one
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