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(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid

(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid

CAS号：890016-81-6

英文名：(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid

分子式

C38H66O8Si

熔点

密度

分子量

679.011

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid

英文名称

(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid

中文别名

英文别名

(R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid

CAS号

890016-81-6

分子式

C38H66O8Si

分子量

679.011

精确质量

678.453

PSA

92.68

LOGP

9.0896

合成路线

共找到4条合成路线 >

(2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentanal

(2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentanal

(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid

(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid

上游原料

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(2R,3S,4S,5R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-(tert-butyldimethylsilyloxy)-2,4-dimethyl-5-(triisopropylsilyloxy)heptan-1-one

(2R,3S,4S,5R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-(tert-butyldimethylsilyloxy)-2,4-dimethyl-5-(triisopropylsilyloxy)heptan-1-one

(4R)-4-benzyl-3-{(2R)-2-[(4S,5R,6R)-6-((1S,2R,3R)-3-{(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyldimethylsiloxy)-1-methylbutyl]-2-(p-methoxyphenyl)-5-methyl-m-dioxan-4-yl}-2-hydroxy-1-methylbutyl)-2,2,5-trimethyl-m-dioxan-4-yl]propionyl}-2-oxazolidinone.....

(4R)-4-benzyl-3-{(2R)-2-[(4S,5R,6R)-6-((1S,2R,3R)-3-{(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyldimethylsiloxy)-1-methylbutyl]-2-(p-methoxyphenyl)-5-methyl-m-dioxan-4-yl}-2-hydroxy-1-methylbutyl)-2,2,5-trimethyl-m-dioxan-4-yl]propionyl}-2-oxazolidinone.....

(2R,3S,4S,5S,6S,7R)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-ol

(2R,3S,4S,5S,6S,7R)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-ol

(2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-methyl-3-(triisopropylsilyloxy)pentan-1-one

(2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-methyl-3-(triisopropylsilyloxy)pentan-1-one

(2S,3R,4R,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-2,4,6-trimethyl-3-triethylsilanyloxy-7-triisopropylsilanyloxy-nonane

(2S,3R,4R,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-2,4,6-trimethyl-3-triethylsilanyloxy-7-triisopropylsilanyloxy-nonane

(2S,3R,4S,5R,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-2,4,6-trimethyl-7-(triisopropylsilyloxy)nonan-1-one

(2S,3R,4S,5R,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-2,4,6-trimethyl-7-(triisopropylsilyloxy)nonan-1-one

下游产品

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(1S,2R,4S,5S,9S,10R,13R,14S,15S,17R,19S,20R)-13-Ethyl-17-(4-methoxy-phenyl)-2,4,7,7,10,14,19,20-octamethyl-6,8,12,16,18-pentaoxa-tricyclo[13.3.1.15,9]icosan-11-one

(1S,2R,4S,5S,9S,10R,13R,14S,15S,17R,19S,20R)-13-Ethyl-17-(4-methoxy-phenyl)-2,4,7,7,10,14,19,20-octamethyl-6,8,12,16,18-pentaoxa-tricyclo[13.3.1.15,9]icosan-11-one

(9S)-6,12-Dideoxy-9-deoxo-9-hydroxy-3,5-O-(1-methylethylidene)erythronolide A ((9S)-Dihydro-6-deoxy-erythronolide B) 3,5-Acetonide

(9S)-6,12-Dideoxy-9-deoxo-9-hydroxy-3,5-O-(1-methylethylidene)erythronolide A ((9S)-Dihydro-6-deoxy-erythronolide B) 3,5-Acetonide

(1S,2R,5R,6R,7S,8R,10R,12S,13S,17R)-5-Ethyl-7-hydroxy-2,6,8,10,12,15,15,17-octamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione

(1S,2R,5R,6R,7S,8R,10R,12S,13S,17R)-5-Ethyl-7-hydroxy-2,6,8,10,12,15,15,17-octamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione

(R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6S)-6-((1S,2R)-2-Hydroxy-1-methyl-butyl)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid

(R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6S)-6-((1S,2R)-2-Hydroxy-1-methyl-butyl)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid

上游原料

(2R,3S,4S,5R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-(tert-butyldimethylsilyloxy)-2,4-dimethyl-5-(triisopropylsilyloxy)heptan-1-one (4R)-4-benzyl-3-{(2R)-2-[(4S,5R,6R)-6-((1S,2R,3R)-3-{(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyldimethylsiloxy)-1-methylbutyl]-2-(p-methoxyphenyl)-5-methyl-m-dioxan-4-yl}-2-hydroxy-1-methylbutyl)-2,2,5-trimethyl-m-dioxan-4-yl]propionyl}-2-oxazolidinone..... (2R,3S,4S,5S,6S,7R)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-ol (2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-methyl-3-(triisopropylsilyloxy)pentan-1-one (2S,3R,4R,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-2,4,6-trimethyl-3-triethylsilanyloxy-7-triisopropylsilanyloxy-nonane (2S,3R,4S,5R,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-2,4,6-trimethyl-7-(triisopropylsilyloxy)nonan-1-one (2R,3S,4S,6R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-6-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3-hydroxy-2,4-dimethyl-heptan-1-one (2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentanal (R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propan-1-one (2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-2-methylpentan-1-one (2S,3R,4R,5S,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-one (R)-4-benzyl-3-((R)-2-((4S,5R,6S)-6-((2S,3R,4R)-4-((2R,4S,5S,6R)-6-((2R,3R)-3-((tert-butyldimethylsilyl)oxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxypentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoyl)oxazolidin-2-one (2S,3R)-2-methyl-3-(triisopropylsilyloxy)pentanal (2R,3S,4S,5S,6S,8R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-8-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3-hydroxy-2,4,6-trimethyl-5-triethylsilanyloxy-nonan-1-one (R)-4-Benzyl-3-[(R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionyl]-oxazolidin-2-one (2S,3R)-2-((4R,5R,6R)-6-((S)-1-iodopropan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-3-ol (2R,3S,4R,5R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-2,4-dimethyl-5-(triisopropylsilyloxy)heptan-1-one (2S,4R)-4-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-methyl-pentanoic acid ((1R,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide (2R,3S,4R,5S,6S,8R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-8-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3,5-dihydroxy-2,4,6-trimethyl-nonan-1-one (2R,3S,4S,5R)-3-(tert-butyldimethylsilyloxy)-2,4-dimethyl-5-(triisopropylsilyloxy)heptanal (2R,3S,4S,6R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-6-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2,4-dimethyl-3-triethylsilanyloxy-heptan-1-one

下游产品

(1S,2R,4S,5S,9S,10R,13R,14S,15S,17R,19S,20R)-13-Ethyl-17-(4-methoxy-phenyl)-2,4,7,7,10,14,19,20-octamethyl-6,8,12,16,18-pentaoxa-tricyclo[13.3.1.15,9]icosan-11-one (9S)-6,12-Dideoxy-9-deoxo-9-hydroxy-3,5-O-(1-methylethylidene)erythronolide A ((9S)-Dihydro-6-deoxy-erythronolide B) 3,5-Acetonide (1S,2R,5R,6R,7S,8R,10R,12S,13S,17R)-5-Ethyl-7-hydroxy-2,6,8,10,12,15,15,17-octamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione (R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6S)-6-((1S,2R)-2-Hydroxy-1-methyl-butyl)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid