百科

(2S,4R)-4-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-methyl-pentanoic acid ((1R,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide

CAS号：890016-94-1

英文名：(2S,4R)-4-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-methyl-pentanoic acid ((1R,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide

分子式：C39H63NO6Si

分子量：670.006

合成路线

890016-91-8

(2S,3R,4R,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-2,4,6-trimethyl-3-triethylsilanyloxy-7-triisopropylsilanyloxy-nonane

890016-94-1

(2S,4R)-4-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-methyl-pentanoic acid ((1R,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide

890016-86-1

(2S,3R,4S,5R,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-2,4,6-trimethyl-7-(triisopropylsilyloxy)nonan-1-one

890016-94-1

890016-82-7

(2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-2-methylpentan-1-one

890016-94-1

890016-87-2

(2S,3R,4R,5S,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-one

890016-94-1

890017-02-4

(2R,3S,4S,5S,6S,7R)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-ol

890016-94-1

890016-99-6

(2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-methyl-3-(triisopropylsilyloxy)pentan-1-one

890016-94-1

上游原料

(2S,3R,4R,5S,6S,7R)-5-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-2,4,6-trimethyl-3-triethylsilanyloxy-7-triisopropylsilanyloxy-nonane (2S,3R,4S,5R,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-2,4,6-trimethyl-7-(triisopropylsilyloxy)nonan-1-one (2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-2-methylpentan-1-one (2S,3R,4R,5S,6S,7R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-one (2R,3S,4S,5S,6S,7R)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyl-3-(triethylsilyloxy)-7-(triisopropylsilyloxy)nonan-1-ol (2S,3R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-methyl-3-(triisopropylsilyloxy)pentan-1-one

下游产品

(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid (2R,3S,4S,6R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-6-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3-hydroxy-2,4-dimethyl-heptan-1-one (2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-2-methylpentanal (R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propan-1-one (2R,3S,4S,5S,6S,8R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-8-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3-hydroxy-2,4,6-trimethyl-5-triethylsilanyloxy-nonan-1-one (2R,3S,4S,6R)-1-((R)-4-Benzyl-2-thioxo-thiazolidin-3-yl)-6-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2,4-dimethyl-3-triethylsilanyloxy-heptan-1-one