百科

Acetic acid (R)-1-{2-[(1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-methylene-octyl]-[1,3]dithian-2-yl}-2-[(2R,4S,5S)-4-methyl-5-((S)-5-methyl-6-oxo-hexyl)-tetrahydro-furan-2-yl]-ethyl ester

CAS号：900159-66-2

英文名：Acetic acid (R)-1-{2-[(1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-methylene-octyl]-[1,3]dithian-2-yl}-2-[(2R,4S,5S)-4-methyl-5-((S)-5-methyl-6-oxo-hexyl)-tetrahydro-furan-2-yl]-ethyl ester

分子式：C36H66O5S2Si

分子量：671.122

合成路线

900152-61-6

(2S,3S,5R)-2-Allyl-3-methyl-5-trityloxymethyl-tetrahydro-furan

900159-66-2

Acetic acid (R)-1-{2-[(1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-methylene-octyl]-[1,3]dithian-2-yl}-2-[(2R,4S,5S)-4-methyl-5-((S)-5-methyl-6-oxo-hexyl)-tetrahydro-furan-2-yl]-ethyl ester

900159-36-6

(2S,3S,5R)-2-((S)-6-Benzyloxy-5-methyl-hexyl)-3-methyl-5-trityloxymethyl-tetrahydro-furan

900159-66-2

Acetic acid (R)-1-{2-[(1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-methylene-octyl]-[1,3]dithian-2-yl}-2-[(2R,4S,5S)-4-methyl-5-((S)-5-methyl-6-oxo-hexyl)-tetrahydro-furan-2-yl]-ethyl ester

900159-33-3

3-((2S,3S,5R)-3-Methyl-5-trityloxymethyl-tetrahydro-furan-2-yl)-propan-1-ol

900159-66-2

Acetic acid (R)-1-{2-[(1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-methylene-octyl]-[1,3]dithian-2-yl}-2-[(2R,4S,5S)-4-methyl-5-((S)-5-methyl-6-oxo-hexyl)-tetrahydro-furan-2-yl]-ethyl ester

上游原料

(2S,3S,5R)-2-Allyl-3-methyl-5-trityloxymethyl-tetrahydro-furan 3-((2S,3S,5R)-3-Methyl-5-trityloxymethyl-tetrahydro-furan-2-yl)-propan-1-ol (2S,3S,5R)-2-((S)-6-Benzyloxy-5-methyl-hexyl)-3-methyl-5-trityloxymethyl-tetrahydro-furan

下游产品

amphidinolide T3 (S)-6-((2S,3S,5R)-5-{(R)-2-Acetoxy-2-[2-((1R,5R)-5-hydroxy-1-methyl-3-methylene-octyl)-[1,3]dithian-2-yl]-ethyl}-3-methyl-tetrahydro-furan-2-yl)-2-methyl-hexanoic acid