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(3S,4S)-3-[(R)-1-(叔丁基二甲基硅氧基)乙基]-4-[(R)-1-羰乙基]-2-氮杂环丁酮

(3S,4S)-3-[(R)-1-(叔丁基二甲基硅氧基)乙基]-4-[(R)-1-羰乙基]-2-氮杂环丁酮

CAS号：90776-58-2
英文名：Side chain for imipenem
分子式
C14H27NO4Si
熔点
146-147°C
密度
1.05 g/cm3
分子量
301.454
沸点
424.4ºC at760mmHg
溶解度
信号词
危险品标志
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基本信息
中文名称
(3S,4S)-3-[(R)-1-(叔丁基二甲基硅氧基)乙基]-4-[(R)-1-羰乙基]-2-氮杂环丁酮
英文名称
Side chain for imipenem
中文别名
(3S,4S)-3-((R)-1-(叔丁基二甲基硅氧基)乙基)-4((R)-1-甲酰乙基)-2-氮杂环丁酮、培南类主环中间体、培南类中间体
英文别名
4-BMA、1-Bma Or 4-Bma、Side chain for iMipe、1-BMA、B-METHYLAZETIDIN-2-ONE、SS-METHYLAZETIDIN-2-ONE
CAS号
90776-58-2
分子式
C14H27NO4Si
分子量
301.454
精确质量
301.171
PSA
75.63
LOGP
2.5608
编号系统
MDL号
MFCD00272297
物化性质
密度
1.05 g/cm3
沸点
424.4ºC at760mmHg
熔点
146-147°C
闪点
210.5ºC
折射率
1.471
安全信息
安全说明
S22; S24/25
WGK Germany
3
生产方法及用途
用途
用于合成美罗培南。
合成路线
共找到23条合成路线 >
(3R,4R)-4-acetoxy-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-2-oxoazetidine
76899-07-5
(3R,4R)-4-acetoxy-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-2-oxoazetidine
2-[(E)-1-(tert-Butyl-dimethyl-silanyloxy)-propenylsulfanylmethyl]-3-methyl-pyridine
117481-73-9
2-[(E)-1-(tert-Butyl-dimethyl-silanyloxy)-propenylsulfanylmethyl]-3-methyl-pyridine
93711-85-4
(2R)-2-[(2S,3S)-3-{(1R)-1-(t-butyldimethylsilyloxy)ethyl}-4-oxoazetidin-2-yl]propionic acid
97101-07-0
(2R)-2-[(2S,3S)-3-{(1R)-1-(t-butyldimethylsilyloxy)ethyl}-4-oxoazetidin-2-yl]propionic acid
(3S,4S)-3-[(R)-1-(叔丁基二甲基硅氧基)乙基]-4-[(R)-1-羰乙基]-2-氮杂环丁酮
90776-58-2
(3S,4S)-3-[(R)-1-(叔丁基二甲基硅氧基)乙基]-4-[(R)-1-羰乙基]-2-氮杂环丁酮
上游原料
共找到3个上游原料 >
(3S,4R)-3-<(1R)-1-<(tert-Butyldimethylsilyl)oxy>ethyl>-4-<(1R)-1-<((4S)-4-isopropyl-2-thioxo-1,3-thiazolidin-3-yl)carbonyl>ethyl>azetidin-2-one
102832-08-6
(3S,4R)-3-<(1R)-1-<(tert-Butyldimethylsilyl)oxy>ethyl>-4-<(1R)-1-<((4S)-4-isopropyl-2-thioxo-1,3-thiazolidin-3-yl)carbonyl>ethyl>azetidin-2-one
(3R,4R)-4-acetoxy-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-2-oxoazetidine
76899-07-5
(3R,4R)-4-acetoxy-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-2-oxoazetidine
2-[(E)-1-(tert-Butyl-dimethyl-silanyloxy)-propenylsulfanylmethyl]-3-methyl-pyridine
117481-73-9
2-[(E)-1-(tert-Butyl-dimethyl-silanyloxy)-propenylsulfanylmethyl]-3-methyl-pyridine
下游产品
共找到23个下游商品 >
(3S,4S)-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]-1-[[(p-nitrobenzyl)oxy]oxalyl]-4-[(R)-1-[[(R)-2-oxopyrrolidin-4-ylthio]carbonyl]ethyl]-2-azetidinone
263020-24-2
(3S,4S)-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]-1-[[(p-nitrobenzyl)oxy]oxalyl]-4-[(R)-1-[[(R)-2-oxopyrrolidin-4-ylthio]carbonyl]ethyl]-2-azetidinone
4-nitrobenzyl 2-((3S,4S)-3-((R)-1-((tert-butyldimethylsilyl)oxy)ethyl)-2-oxo-4-((R)-1-oxo-1-(((R)-5-oxopyrrolidin-3-yl)thio)propan-2-yl)azetidin-1-yl)-2-(triethoxy-l5-phosphaneylidene)acetate
263020-25-3
4-nitrobenzyl 2-((3S,4S)-3-((R)-1-((tert-butyldimethylsilyl)oxy)ethyl)-2-oxo-4-((R)-1-oxo-1-(((R)-5-oxopyrrolidin-3-yl)thio)propan-2-yl)azetidin-1-yl)-2-(triethoxy-l5-phosphaneylidene)acetate
pivaloyloxymethyl (1R,5S,6S)-6-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-2-[(3S,5S)-5-(N,N-dimethylcarbamoyl)-1-(isobutyryloxymethyloxycarbonyl)pyrrolidin-3-ylthio]-1-methylcarbapen-2-em-3-carboxylate
311815-52-8
pivaloyloxymethyl (1R,5S,6S)-6-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-2-[(3S,5S)-5-(N,N-dimethylcarbamoyl)-1-(isobutyryloxymethyloxycarbonyl)pyrrolidin-3-ylthio]-1-methylcarbapen-2-em-3-carboxylate
(1R,5R,6S)-2-<4'-(aminomethyl)phenyl>-6-<(1R)-1-hydroxyethyl>-1-methylcarbapen-2-em-3-carboxylic acid
75486-55-4
(1R,5R,6S)-2-<4'-(aminomethyl)phenyl>-6-<(1R)-1-hydroxyethyl>-1-methylcarbapen-2-em-3-carboxylic acid
杂氮双环磷酸酯
90776-59-3
杂氮双环磷酸酯
(4R,5S,6S)-4-Methyl-7-oxo-3-((R)-5-oxo-1-triethylsilanyl-pyrrolidin-3-ylsulfanyl)-6-((R)-1-trimethylsilanyloxy-ethyl)-1-aza-bicyclo[3.2.0]hept-2-ene-2-carboxylic acid 2,2-dimethyl-propionyloxymethyl ester
263020-32-2
(4R,5S,6S)-4-Methyl-7-oxo-3-((R)-5-oxo-1-triethylsilanyl-pyrrolidin-3-ylsulfanyl)-6-((R)-1-trimethylsilanyloxy-ethyl)-1-aza-bicyclo[3.2.0]hept-2-ene-2-carboxylic acid 2,2-dimethyl-propionyloxymethyl ester
上游原料
(3S,4R)-3-<(1R)-1-<(tert-Butyldimethylsilyl)oxy>ethyl>-4-<(1R)-1-<((4S)-4-isopropyl-2-thioxo-1,3-thiazolidin-3-yl)carbonyl>ethyl>azetidin-2-one (3R,4R)-4-acetoxy-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-2-oxoazetidine 2-[(E)-1-(tert-Butyl-dimethyl-silanyloxy)-propenylsulfanylmethyl]-3-methyl-pyridine
下游产品
(3S,4S)-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]-1-[[(p-nitrobenzyl)oxy]oxalyl]-4-[(R)-1-[[(R)-2-oxopyrrolidin-4-ylthio]carbonyl]ethyl]-2-azetidinone 4-nitrobenzyl 2-((3S,4S)-3-((R)-1-((tert-butyldimethylsilyl)oxy)ethyl)-2-oxo-4-((R)-1-oxo-1-(((R)-5-oxopyrrolidin-3-yl)thio)propan-2-yl)azetidin-1-yl)-2-(triethoxy-l5-phosphaneylidene)acetate pivaloyloxymethyl (1R,5S,6S)-6-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-2-[(3S,5S)-5-(N,N-dimethylcarbamoyl)-1-(isobutyryloxymethyloxycarbonyl)pyrrolidin-3-ylthio]-1-methylcarbapen-2-em-3-carboxylate (1R,5R,6S)-2-<4'-(aminomethyl)phenyl>-6-<(1R)-1-hydroxyethyl>-1-methylcarbapen-2-em-3-carboxylic acid 杂氮双环磷酸酯 (4R,5S,6S)-4-Methyl-7-oxo-3-((R)-5-oxo-1-triethylsilanyl-pyrrolidin-3-ylsulfanyl)-6-((R)-1-trimethylsilanyloxy-ethyl)-1-aza-bicyclo[3.2.0]hept-2-ene-2-carboxylic acid 2,2-dimethyl-propionyloxymethyl ester (3S,4S)-4-[(R)-1-[[(R)-2-oxo-1-(triethylsilyl)pyrrolidin-4-ylthio]carbonyl]ethyl]-1-[[(pivaloyloxy)methyloxy]oxalyl]-3-[(R)-1-(trimethylsilyloxy)ethyl]-2-azetidinone 4-nitrobenzyl 2-((3S,4S)-3-((R)-1-((tert-butyldimethylsilyl)oxy)ethyl)-2-oxo-4-((R)-1-oxo-1-(((R)-5-oxopyrrolidin-3-yl)thio)propan-2-yl)azetidin-1-yl)-2-(diethoxy(ethyl)-l5-phosphaneylidene)acetate (3S,4S)-3-<(tert-butyldimethylsiloxy)methyl>-4-<1(R)-(methoxycarbonyl)ethyl>azetidin-2-one (R)-2-[(2S,3S)-4-Oxo-3-((R)-1-triethylsilanyloxy-ethyl)-azetidin-2-yl]-thiopropionic acid S-((R)-5-oxo-1-triethylsilanyl-pyrrolidin-3-yl) ester [(3S,4S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-oxo-4-((R)-1-phenylsulfanylcarbonyl-ethyl)-azetidin-1-yl]-acetic acid allyl ester potassium (1R,5R,6S)-2-(3'-pyridyl)-6-<(1R)-1-hydroxyethyl>-1-methylcarbapen-2-em-3-carboxylate (3S,4S)-3-[(R)-1-[[(R)-2-oxopyrrolidin-4-ylthio]carbonyl]ethyl]-3-[(R)-1-(triethylsilyloxy)ethyl]-2-azetidinone (R)-2-[(2S,3S)-3-((S)-1-Hydroxy-ethyl)-4-oxo-azetidin-2-yl]-propionic acid benzyl ester potassium (1R,5R,6S)-2-<4'-(hydroxymethyl)phenyl>-6-<(1R)-1-hydroxyethyl>-1-methylcarbapen-2-em-3-carboxylate (2S,5R,6S,7S)-7-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-5-methyl-4,8-dioxo-3-thia-1-aza-bicyclo[4.2.0]octane-2-carboxylic acid 2,2-dimethyl-propionyloxymethyl ester (3S,4S)-3-[(R)-1-[[(R)-2-oxopyrrolidin-4-ylthio]carbonyl]ethyl]-3-[(R)-1-(trimethylsilyloxy)ethyl]-2-azetidinone (4S,5R,6S)-6-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3-[1,3]dithian-2-ylidene-4-methyl-7-oxo-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid benzhydryl ester (2-(diethoxy(ethyl)-l5-phosphaneylidene)-2-((3S,4S)-2-oxo-4-((R)-1-oxo-1-(((R)-5-oxo-1-(triethylsilyl)pyrrolidin-3-yl)thio)propan-2-yl)-3-((R)-1-((trimethylsilyl)oxy)ethyl)azetidin-1-yl)acetoxy)methyl pivalate pivaloyloxymethyl (4R)-{(2R,3S)-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-4-oxoazetidin-2-y}-2-diaza-3-oxopentanoate (3S,4S)-1-(allyloxycarbonylmethyl)-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-4-[(1R)-1-carboxyethyl]-2-azetidinone pivaloyloxymethyl (4R)-{(2R,3S)-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-4-oxoazetidin-2-y}-3-oxopentanoate potassium (1R,5R,6S)-2-phenyl-6-<(1R)-1-hydroxyethyl>-1-methylcarbapen-2-em-3-carboxylate
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