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(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

CAS号：911708-86-6

英文名：(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

分子式：C11H22O

分子量：170.292

合成路线

(2S,4E)-2,4-dimethyl-4-hexenal

(2S,4E)-2,4-dimethyl-4-hexenal

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

(-)-tert-butyldiphenyl((2S,4R,E)-2,4,6-trimethyloct-6-enyloxy)silane

(-)-tert-butyldiphenyl((2S,4R,E)-2,4,6-trimethyloct-6-enyloxy)silane

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

(-)-tert-butyl-((2S,4R)-2,4-dimethylhept-6-ynyloxy)diphenylsilane

(-)-tert-butyl-((2S,4R)-2,4-dimethylhept-6-ynyloxy)diphenylsilane

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

(-)-tert-butyl-((2S,4R,E)-7-iodo-2,4,6-trimethylhept-6-enyloxy)diphenylsilane

(-)-tert-butyl-((2S,4R,E)-7-iodo-2,4,6-trimethylhept-6-enyloxy)diphenylsilane

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

(-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol

上游原料

(-)-tert-butyl-((2S,4R,E)-7-iodo-2,4,6-trimethylhept-6-enyloxy)diphenylsilane (2S,4E)-2,4-dimethyl-4-hexenal (-)-tert-butyl-((2S,4R)-2,4-dimethylhept-6-ynyloxy)diphenylsilane (-)-tert-butyldiphenyl((2S,4R,E)-2,4,6-trimethyloct-6-enyloxy)silane

下游产品

(-)-(5R,6R)-6-((2S,4R,E)-4,6-dimethyloct-6-en-2-yl)-5-hydroxy-5,6-dihydro-2H-pyran-2-one (5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone (R)-6-((2S,4R,E)-4,6-dimethyloct-6-en-2-yl)-2H-pyran-2,5(6H)-dione (2R)-2-((2S,4R,E)-4,6-dimethyloct-6-en-2-yl)-6-hydroxy-2H-pyran-3(6H)-one