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(4a'R,6'S,8'R,8a'S)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol

(4a'R,6'S,8'R,8a'S)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol

CAS号：95791-27-8

英文名：(4a'R,6'S,8'R,8a'S)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol

分子式

C26H42O7

熔点

密度

分子量

466.607

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(4a'R,6'S,8'R,8a'S)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol

英文名称

(4a'R,6'S,8'R,8a'S)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol

中文别名

英文别名

CAS号

95791-27-8

分子式

C26H42O7

分子量

466.607

精确质量

466.293

PSA

86.61

LOGP

3.4556

合成路线

(2R,4a'R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)-6'-((S)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)but-1-en-1-yl)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]

(2R,4a'R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)-6'-((S)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)but-1-en-1-yl)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]

(4a'R,6'S,8'R,8a'S)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol

(4a'R,6'S,8'R,8a'S)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol

上游原料

共找到4个上游原料 >

(2S,3R,6S)-2-((R)-2-Bromo-1-methyl-ethyl)-3-methyl-1,7-dioxa-spiro[5.5]undecane

(2S,3R,6S)-2-((R)-2-Bromo-1-methyl-ethyl)-3-methyl-1,7-dioxa-spiro[5.5]undecane

(2R,4a'R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)-6'-((S)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)but-1-en-1-yl)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]

(2R,4a'R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)-6'-((S)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)but-1-en-1-yl)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]

(1S,3R)-1-((4a'R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)-2-(phenylsulfonyl)butan-1-ol

(1S,3R)-1-((4a'R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)-2-(phenylsulfonyl)butan-1-ol

(3R)-1-((4a'R,6'S,7'S,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)-2-(phenylsulfonyl)butan-1-one

(3R)-1-((4a'R,6'S,7'S,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)-2-(phenylsulfonyl)butan-1-one

上游原料

(2S,3R,6S)-2-((R)-2-Bromo-1-methyl-ethyl)-3-methyl-1,7-dioxa-spiro[5.5]undecane (2R,4a'R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)-6'-((S)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)but-1-en-1-yl)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran] (1S,3R)-1-((4a'R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)-2-(phenylsulfonyl)butan-1-ol (3R)-1-((4a'R,6'S,7'S,8'R,8a'R)-7'-(benzyloxy)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)-2-(phenylsulfonyl)butan-1-one