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3,5,6-trideoxy-1,2-O-isopropylidene-α-D-ribo-hex-5-enofuranoside

3,5,6-trideoxy-1,2-O-isopropylidene-α-D-ribo-hex-5-enofuranoside

CAS号：96852-88-9

英文名：3,5,6-trideoxy-1,2-O-isopropylidene-α-D-ribo-hex-5-enofuranoside

分子式

C9H14O3

熔点

密度

分子量

170.206

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

3,5,6-trideoxy-1,2-O-isopropylidene-α-D-ribo-hex-5-enofuranoside

英文名称

3,5,6-trideoxy-1,2-O-isopropylidene-α-D-ribo-hex-5-enofuranoside

中文别名

英文别名

(3aR,5S,6aR)-2,2-Dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

CAS号

96852-88-9

分子式

C9H14O3

分子量

170.206

精确质量

170.094

PSA

27.69

LOGP

1.4389

合成路线

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α-D-1,2:5,6-di-O-isopropylidene-3-O-[(methylthio)thiocarbonyl]-glucofuranose

α-D-1,2:5,6-di-O-isopropylidene-3-O-[(methylthio)thiocarbonyl]-glucofuranose

3,5,6-trideoxy-1,2-O-isopropylidene-α-D-ribo-hex-5-enofuranoside

3,5,6-trideoxy-1,2-O-isopropylidene-α-D-ribo-hex-5-enofuranoside

上游原料

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1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

α-D-1,2:5,6-di-O-isopropylidene-3-O-[(methylthio)thiocarbonyl]-glucofuranose

α-D-1,2:5,6-di-O-isopropylidene-3-O-[(methylthio)thiocarbonyl]-glucofuranose

1,2-O-isopropylidene-3-deoxy-5,6-di-O-methylsulphonyl-α-D-glucofuranose

1,2-O-isopropylidene-3-deoxy-5,6-di-O-methylsulphonyl-α-D-glucofuranose

(1S)-1-[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol

(1S)-1-[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol

(3aR,5S,6aR)-5-(2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5S,6aR)-5-(2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole

(3aR,5S,6aR)-2,2-Dimethyl-5-((R)-2-oxo-2λ4-[1,3,2]dioxathiolan-4-yl)-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5S,6aR)-2,2-Dimethyl-5-((R)-2-oxo-2λ4-[1,3,2]dioxathiolan-4-yl)-tetrahydro-furo[2,3-d][1,3]dioxole

下游产品

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2H-Pyran-2-one, 5,6-dihydro-6-(hydroxymethyl)-, (6R)-

2H-Pyran-2-one, 5,6-dihydro-6-(hydroxymethyl)-, (6R)-

methyl (3S,5R,6E)-7-phenyl-3,5-isopropylidenedioxy-6-heptenoate

methyl (3S,5R,6E)-7-phenyl-3,5-isopropylidenedioxy-6-heptenoate

(4S,6R)-4-Hydroxy-6-((Z)-styryl)-tetrahydro-pyran-2-one

(4S,6R)-4-Hydroxy-6-((Z)-styryl)-tetrahydro-pyran-2-one

(R)-6,6-Dibromo-hex-5-en-3-ol

(R)-6,6-Dibromo-hex-5-en-3-ol

Benzoic acid (R)-1-ethyl-but-3-ynyl ester

Benzoic acid (R)-1-ethyl-but-3-ynyl ester

[(2R,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclopentyl]-acetic acid methyl ester

[(2R,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclopentyl]-acetic acid methyl ester

上游原料

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose α-D-1,2:5,6-di-O-isopropylidene-3-O-[(methylthio)thiocarbonyl]-glucofuranose 1,2-O-isopropylidene-3-deoxy-5,6-di-O-methylsulphonyl-α-D-glucofuranose (1S)-1-[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol (3aR,5S,6aR)-5-(2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole (3aR,5S,6aR)-2,2-Dimethyl-5-((R)-2-oxo-2λ4-[1,3,2]dioxathiolan-4-yl)-tetrahydro-furo[2,3-d][1,3]dioxole 3-deoxy-1,2-O-isopropylidene-α-D-ribo-hexofuranose

下游产品

methyl (3S,5R,6E)-7-phenyl-3,5-isopropylidenedioxy-6-heptenoate (4S,6R)-4-Hydroxy-6-((Z)-styryl)-tetrahydro-pyran-2-one (R)-6,6-Dibromo-hex-5-en-3-ol Benzoic acid (R)-1-ethyl-but-3-ynyl ester [(2R,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-hydroxymethyl-cyclopentyl]-acetic acid methyl ester Formic acid (R)-4,4-dibromo-1-ethyl-but-3-enyl ester ((2S,4R,6R)-4-Benzyloxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-yl)-acetic acid ethyl ester 6-[4-benzyloxy-6-methoxymethoxymethyl-(2S,4R,6R)-2H,3H,4H,5H-2-pyranylmethyl]-(6R)-2H,5H-2-pyranone (2R,4S)-5-hexene-1,2,4-triol (4S,6R)-6-((Z)-Hept-1-enyl)-4-hydroxy-tetrahydro-pyran-2-one ((1S,3R)-3-Benzyloxy-4-trityloxy-1-vinyl-butoxy)-tert-butyl-diphenyl-silane [(4S,6R)-2,2-Dimethyl-6-((Z)-styryl)-[1,3]dioxan-4-yl]-acetic acid methyl ester Methyl 6-O-benzyl-3,5-dideoxy-2-methylthiocarbonyl (β)-D-erythrohexofuranoside methyl (3S,5R)-3,5-isopropylidenedioxy-6-oxohexanoate (2R,3S,6S,8R)-3-(tert-Butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-2-methyl-decanoic acid (2R,4S)-2-Benzyloxy-hex-5-ene-1,4-diol 3,5,6-Tridesoxy-1,2-O-isopropyliden-α-D-erythro-hexofuranose (4S,6R)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-octanal [(4S,6R)-6-((Z)-Hept-1-enyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-acetic acid methyl ester (3S,5R)-5-Benzyloxy-6-trityloxy-hex-1-en-3-ol (3S,5R)-6,6-Bis-ethylsulfanyl-3,5-dihydroxy-hexanoic acid methyl ester [(4S,6R)-6-(Bis-ethylsulfanyl-methyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-acetic acid methyl ester ethyl 5-benzyloxy-7,8-dihydroxy-(E,5R,7R)-2-octenoate (3R,5S)-3-Benzyloxy-2-methoxy-5-vinyl-tetrahydro-furan Methyl 6-O-benzyl-2,3,5-trideoxy-(β)-D-glycerohexofuranoside 3-benzyloxy-4-[2,2-dimethyl-(4R)-1,3-dioxolan-4-yl]-(3R)-butan-1-ol (R)-4-((S)-2-Benzyloxy-but-3-enyl)-2,2-dimethyl-[1,3]dioxolane ethyl 5-benzyloxy-6-[2,2-dimethyl-(4R)-1,3-dioxolan-4-yl]-(E,5R)-2-hexenoate ((2S,4R,6R)-4-Benzyloxy-6-hydroxymethyl-tetrahydro-pyran-2-yl)-acetic acid ethyl ester feigrisolide B Methyl 6-O-benzyl-3,5-dideoxy-(β-)-D-erythrohexofuranoside 4-benzyloxy-2-[2-ethoxy-(2S,6R)-2H,5H-6-pyranylmethyl]-6-methoxymethoxymethyl-(2R,4R,6R)-2H,3H,4H,5H-pyran (R)-6-Oxo-3,6-dihydro-2H-pyran-2-carbaldehyde (4S,6R)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-octan-1-ol (3R,4S,7S)-4-(tert-Butyl-dimethyl-silanyloxy)-7-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-butyl]-3-methyl-oxepan-2-one (4S,6R)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-octanoic acid ethyl ester (2R,3S,6S,8R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-2-methyl-decanoic acid 6-O-Benzyl-3,5-dideoxy-1,2-O-isopropylidene-α-D-erythro-hexofuranose (E)-(4R,6S)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-octa-2,7-dienoic acid ethyl ester (2R,3S,6S,8R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-2-methyl-decanal ((2S,4R,6R)-4-Benzyloxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-yl)-acetaldehyde (2R,4S)-2-Benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-hex-5-enal (R)-1-((2R,4R,6R)-4-Benzyloxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-yl)-pent-4-en-2-ol (2R,4S)-2-Benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-hex-5-en-1-ol Acrylic acid (R)-1-((2S,4R,6R)-4-benzyloxy-6-methoxymethoxymethyl-tetrahydro-pyran-2-ylmethyl)-but-3-enyl ester