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3,5:9,11-di-O-isopropylidene.(9S)-9-deoxo-hydroxyerythronolide

3,5:9,11-di-O-isopropylidene.(9S)-9-deoxo-hydroxyerythronolide

CAS号:99285-07-1
英文名:3,5:9,11-di-O-isopropylidene.(9S)-9-deoxo-hydroxyerythronolide
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基本信息
上游原料
3-O-benzyl-7-O-(t-butyldiphenylsilyl)-1,2-dideoxy-4,5-O-isopropylidene-4-C-methyl-D-manno-heptitol (2S,3R,4S,5R,6R,8R,9S,10S,11R,12R,13R)-2,4,6,8,10,12-Hexamethyl-6,12-bis-triethylsilanyloxy-pentadecane-1,3,5,9,11,13-hexaol (R)-2-((4S,5S,6R)-6-{(1R,3R)-3-[(4S,5S,6R)-6-((1R,2R)-1,2-Dihydroxy-1-methyl-butyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-1-hydroxy-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionaldehyde 3-O-benzyl-1,2-dideoxy-4,5-isopropylidene-4-methyl-D-manno-heptitol 1,3,5,9,11,13-hexa-O-benzyl-2,4,7,8,10,14,15-heptadeoxy-2,4,6,8,10,12-hexa-C-methyl-6,12-di-O-triethylsilyl-D-arabino-D-gluco-L-ido-pentadecitol 1,3,5,13-tetra-O-benzyl-6-O-t-butyldimethylsilyl-2,4,7,8,10,14,15-heptadeoxy-11,12-O-isopropylidene-2,4,6,8,12-penta-C-methyl-10-C-methylene-D-erythro-L-ido-L-ido-pentadecitol (R)-2-((4S,5S,6R)-6-{(1R,3R)-3-[(4S,5S,6R)-6-((1R,2R)-2-Acetoxy-1-hydroxy-1-methyl-butyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-1-hydroxy-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid (2R,3R)-2-((4R,5S,6R)-6-((2R,4R)-4-((4R,5S,6R)-6-((S)-1-((tert-butyldiphenylsilyl)oxy)propan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-4-((triethylsilyl)oxy)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-2-((triethylsilyl)oxy)pentan-3-yl acetate 5-O-benzyl-1,6,7-trideoxy-3,4-O-isopropylidene-4-C-methyl-keto-D-arabino-2-heptulose 5-O-(t-butyldiphenylsilyl)1-deoxy-3,4-O-isopropyldene-2-C-vinyl-D-aribitol (3R,4R,5R,6S,7S,8R,10R,11R,12S,13R,14S)-15-(tert-Butyl-diphenyl-silanyloxy)-4,6,8,10,12,14-hexamethyl-4,10-bis-triethylsilanyloxy-pentadecane-3,5,7,11,13-pentaol 1-O-t-butyldiphenylsilyl-2,4,7,8,10,14,15-heptadeoxy-3,5:9,11-di-O-isopropylidene-2,4,6,8,10,12-hexa-C-methyl-6,12-di-O-triethylsilyl-D-arabino-D-gluco-L-ido-pentadecitol (2R,3R)-2,3-<(R)-(4-methoxybenzylidene)dioxy>-2-methylpentanal 3-O-benzyl-7-O-(t-butyldiphenylsilyl)-1,2-dideoxy-5,6-O-isopropylidene-4-C-methyl-D-manno-heptitol (1S,2R,3R,4R,6R)-6-Benzyloxy-1-[(2R,4S,5R)-5-ethyl-2-(4-methoxy-phenyl)-4-methyl-[1,3]dioxolan-4-yl]-2,4-dimethyl-6-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-heptane-1,3-diol 7-O-(t-butyldiphenylsilyl)-1,2-dideoxy-5,6-O-isopropylidene-4-C-methyl-keto-D-arabino-3-heptulose (4R,5S,6R)-4-((2R,4R)-2-(benzyloxy)-4-((4R,5R,6S)-6-((2R,3R)-2,3-bis(benzyloxy)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)pentan-2-yl)-6-((S)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxane 5,7,9-tri-O-benzyl-2,3,6,8-tetradeoxy-2,4,6,8-tetra-C-methyl-L-threo-L-ido-nonose ethylene acetal
下游产品
1,3,5,9,13-penta-O-benzyl-6-O-t-butyldimethylsilyl-2,4,7,8,10,14,15-heptadeoxy-11,12-O-isopropylidene-2,4,6,8,10,12-hexa-C-methyl-D-arabino-D-gluco-L-ido-pentadecitol (3R,4S,5R,6R,7S,8R,10R,11R,12S,13R,14S)-3,7,11,13,15-Pentakis-benzyloxy-4,6,8,10,12,14-hexamethyl-pentadecane-4,5,10-triol (3aR,4R,7R,8S,9S,10R,11R,13R,15R,15aR)-11-Benzyloxy-4-ethyl-8,10-dihydroxy-3a,7,9,11,13,15-hexamethyl-2-phenyl-decahydro-1,3,5-trioxa-cyclopentacyclotetradecene-6,14-dione (2R,3S,4S)-3-Acetoxy-4-((2R,3R)-6-{(S)-1-[(4S,5S)-5-((R)-1-acetoxy-propyl)-5-methyl-2-oxo-[1,3]dioxolan-4-yl]-ethyl}-3-benzyloxy-3,5-dimethyl-3,4-dihydro-2H-pyran-2-yl)-2-methyl-pentanoic acid methyl ester Benzoic acid (S)-2-[(4R,5S,6R)-6-((1R,3R)-3-{(4S,5S,6R)-6-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-1-methyl-butyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-1-hydroxy-1-methyl-butyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-propyl ester (1S,2R,5R,6R,10R,11R,13R,15R,16R,20S)-15-Benzyloxy-5-ethyl-2,6,11,13,15,18,18,20-octamethyl-8-phenyl-4,7,9,17,19-pentaoxa-tricyclo[14.3.1.06,10]icosane-3,12-dione (2R,3S,4S)-3-Acetoxy-4-((2R,3R)-3-benzyloxy-6-{(S)-1-[(4S,5S)-5-((R)-1-hydroxy-propyl)-5-methyl-2-oxo-[1,3]dioxolan-4-yl]-ethyl}-3,5-dimethyl-3,4-dihydro-2H-pyran-2-yl)-2-methyl-pentanoic acid methyl ester (1S,2R,5R,6S,7R,8S,9S,10R,12R,13R,17S)-6,12-Bis-benzyloxy-5-ethyl-7,9-dihydroxy-2,6,8,10,12,15,15,17-octamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one (3R,4S,5S,6R,7R,9R,10S,11S,12R,13S,14R)-7,13-Bis-benzyloxy-14-ethyl-4,6,10,12-tetrahydroxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradecan-2-one