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<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane
CAS号:103368-49-6
英文名:<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane
分子式:C21H38O3Si
分子量:366.61
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合成路线
103368-43-0
<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran
103368-49-6
<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane
103421-40-5
(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol
103368-49-6
<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane
103368-48-5
<2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran
103368-49-6
<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane
上游原料
(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol
<2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran
<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran
下游产品
methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate
<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane