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<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R-<1β,3β(1S),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

CAS号：103368-49-6

英文名：<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

分子式

C21H38O3Si

熔点

102 - 103 °C

密度

分子量

366.61

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

英文名称

<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

中文别名

英文别名

[1R*-(1β,3β(1S*),4α,5β,6β,8α)]-6-[(tert-butyldimethylsilyl)oxy]-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo[3.3.1]nonane、tert-Butyl-dimethyl-[(1S,3R,4R,5S,6R,8R)-1,4,8-trimethyl-3-((R)-1-methyl-but-2-ynyl)-2,9-dioxa-bicyclo[3.3.1]non-6-yloxy]-silane

CAS号

103368-49-6

分子式

C21H38O3Si

分子量

366.61

精确质量

366.259

PSA

27.69

LOGP

5.2123

物化性质

熔点

102 - 103 °C

合成路线

共找到2条合成路线 >

<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

上游原料

共找到3个上游原料 >

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol

<2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

下游产品

共找到2个下游商品 >

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

上游原料

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol <2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran <2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

下游产品

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate <1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane