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<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R-<1β,3β(1S,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

CAS号：103368-50-9

英文名：<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

分子式

C21H39BrO3Si

熔点

52 - 53 °C

密度

分子量

447.522

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

英文名称

<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

中文别名

英文别名

[1R*-(1β,3β(1S*,2E),4α,5β,6β,8α)]-3-(3-bromo-1-methylbut-2-enyl)-6-[(tert-butyldimethylsilyl)oxy]-1,4,8-trimethyl-2,9-dioxabicyclo[3.3.1]nonane、[(1S,3R,4R,5S,6R,8R)-3-((Z)-(R)-3-Bromo-1-methyl-but-2-enyl)-1,4,8-trimethyl-2,9-dioxa-bicyclo[3.3.1]non-6-yloxy]-tert-butyl-dimethyl-silane

CAS号

103368-50-9

分子式

C21H39BrO3Si

分子量

447.522

精确质量

446.185

PSA

27.69

LOGP

6.4877

物化性质

熔点

52 - 53 °C

合成路线

<1R*-<1α,3α(1S*),4β,5α,6α,8β>>-6-hydroxy-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1α,3α(1S*),4β,5α,6α,8β>>-6-hydroxy-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1β,3β(1S*,2E),4α,5β,6β,8α>>-3-(3-bromo-1-methylbut-2-enyl)-6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

上游原料

共找到5个上游原料 >

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol

<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

<1R*-<1α,3α(1S*),4β,5α,6α,8β>>-6-hydroxy-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1α,3α(1S*),4β,5α,6α,8β>>-6-hydroxy-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

上游原料

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol <1R*-<1β,3β(1S*),4α,5β,6β,8α>>-6-((tert-butyldimethylsilyl)oxy)-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane <2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran <2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran <1R*-<1α,3α(1S*),4β,5α,6α,8β>>-6-hydroxy-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane