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methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

methyl <2E,4E,6R<1S-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

CAS号：103368-52-1

英文名：methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

分子式

C19H30O5

熔点

151 °C

密度

分子量

338.439

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

英文名称

methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

中文别名

英文别名

(2E,4E)-(R)-6-((1S,3R,4R,5S,6R,8R)-6-Hydroxy-1,4,8-trimethyl-2,9-dioxa-bicyclo[3.3.1]non-3-yl)-4-methyl-hepta-2,4-dienoic acid methyl ester、methyl [2E,4E,6R*(1S*-[1α,3α,5α,6α,8β])]-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo[3.3.1]nonan-3-yl)-4-methylhepta-2,4-dionate

CAS号

103368-52-1

分子式

C19H30O5

分子量

338.439

精确质量

338.209

PSA

64.99

LOGP

2.835

物化性质

熔点

151 °C

合成路线

共找到9条合成路线 >

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

上游原料

共找到1个上游原料 >

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

下游产品

共找到9个下游商品 >

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(6-oxo-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(6-oxo-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid

<1R*-<1β,2α,4α,6β,7α,8β(1E,2E,4E,6R*)>>-1-(2,4-dimethoxybenzyl)-3-<1-hydroxy-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienylidene>-2,4-pyrrolidinedione

<1R*-<1β,2α,4α,6β,7α,8β(1E,2E,4E,6R*)>>-1-(2,4-dimethoxybenzyl)-3-<1-hydroxy-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienylidene>-2,4-pyrrolidinedione

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,8S*)>>-N-(2,4-dimethoxybenzyl)-N-(2-ethoxy-2-oxoethyl)-3-oxo-6-methyl-8-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.02,4>dec-8-yl)-4,6-nonadienamide

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,8S*)>>-N-(2,4-dimethoxybenzyl)-N-(2-ethoxy-2-oxoethyl)-3-oxo-6-methyl-8-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.02,4>dec-8-yl)-4,6-nonadienamide

(+/-)-tirandamycin A

(+/-)-tirandamycin A

上游原料

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

下游产品

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(6-oxo-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate <1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid <1R*-<1β,2α,4α,6β,7α,8β(1E,2E,4E,6R*)>>-1-(2,4-dimethoxybenzyl)-3-<1-hydroxy-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienylidene>-2,4-pyrrolidinedione methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate <1R*-<1β,2α,4α,6β,7α,8β(2E,4E,8S*)>>-N-(2,4-dimethoxybenzyl)-N-(2-ethoxy-2-oxoethyl)-3-oxo-6-methyl-8-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.02,4>dec-8-yl)-4,6-nonadienamide (+/-)-tirandamycin A methyl <2E,4E,6S*<1R*-<1β,2α,4α,6β,7α,8β>>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)hepta-2,4-dienoate methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(1,4,8-trimethyl-6-((trimethylsilyl)oxy)-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate tirandamycic acid chloride