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tirandamycic acid chloride

tirandamycic acid chloride

CAS号：103368-55-4

英文名：tirandamycic acid chloride

分子式

C18H23ClO5

熔点

密度

分子量

354.825

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

tirandamycic acid chloride

英文名称

tirandamycic acid chloride

中文别名

英文别名

(2E,4E)-(S)-4-Methyl-6-((1R,2R,4S,6R,7S,8S)-1,2,7-trimethyl-5-oxo-3,9,10-trioxa-tricyclo[4.3.1.02,4]dec-8-yl)-hepta-2,4-dienoyl chloride

CAS号

103368-55-4

分子式

C18H23ClO5

分子量

354.825

精确质量

354.123

PSA

65.13

LOGP

2.7669

合成路线

共找到3条合成路线 >

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate

tirandamycic acid chloride

tirandamycic acid chloride

上游原料

共找到7个上游原料 >

methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(6-oxo-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(6-oxo-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate

methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate

methyl <2E,4E,6S*<1R*-<1β,2α,4α,6β,7α,8β>>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)hepta-2,4-dienoate

methyl <2E,4E,6S*<1R*-<1β,2α,4α,6β,7α,8β>>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)hepta-2,4-dienoate

下游产品

共找到3个下游商品 >

<1R*-<1β,2α,4α,6β,7α,8β(1E,2E,4E,6R*)>>-1-(2,4-dimethoxybenzyl)-3-<1-hydroxy-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienylidene>-2,4-pyrrolidinedione

<1R*-<1β,2α,4α,6β,7α,8β(1E,2E,4E,6R*)>>-1-(2,4-dimethoxybenzyl)-3-<1-hydroxy-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienylidene>-2,4-pyrrolidinedione

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,8S*)>>-N-(2,4-dimethoxybenzyl)-N-(2-ethoxy-2-oxoethyl)-3-oxo-6-methyl-8-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.02,4>dec-8-yl)-4,6-nonadienamide

<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,8S*)>>-N-(2,4-dimethoxybenzyl)-N-(2-ethoxy-2-oxoethyl)-3-oxo-6-methyl-8-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.02,4>dec-8-yl)-4,6-nonadienamide

(+/-)-tirandamycin A

(+/-)-tirandamycin A

上游原料

methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(6-oxo-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate <1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate methyl <2E,4E,6S*<1R*-<1β,2α,4α,6β,7α,8β>>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)hepta-2,4-dienoate methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(1,4,8-trimethyl-6-((trimethylsilyl)oxy)-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate

下游产品

<1R*-<1β,2α,4α,6β,7α,8β(1E,2E,4E,6R*)>>-1-(2,4-dimethoxybenzyl)-3-<1-hydroxy-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienylidene>-2,4-pyrrolidinedione <1R*-<1β,2α,4α,6β,7α,8β(2E,4E,8S*)>>-N-(2,4-dimethoxybenzyl)-N-(2-ethoxy-2-oxoethyl)-3-oxo-6-methyl-8-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.02,4>dec-8-yl)-4,6-nonadienamide (+/-)-tirandamycin A