百科

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

CAS号：107173-84-2

英文名：(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

分子式：C18H30O3Si

分子量：322.515

合成路线

(Z)-己-4-烯醛

(Z)-己-4-烯醛

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(Z)-1-(2-methoxyphenyl)hex-4-en-1-ol

(Z)-1-(2-methoxyphenyl)hex-4-en-1-ol

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(Z)-tert-butyl((1-(2-methoxyphenyl)hex-4-en-1-yl)oxy)dimethylsilane

(Z)-tert-butyl((1-(2-methoxyphenyl)hex-4-en-1-yl)oxy)dimethylsilane

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(3R,3aR,6S,7R,8R,8aS)-3-((tert-butyldimethylsilyl)oxy)-6-hydroxy-8-methyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulen-9-one

(3R,3aR,6S,7R,8R,8aS)-3-((tert-butyldimethylsilyl)oxy)-6-hydroxy-8-methyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulen-9-one

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

顺-4-己烯-1-醇

顺-4-己烯-1-醇

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

(3R,3aS,7S,8R,8aS,9R)-3-((tert-butyldimethylsilyl)oxy)-9-hydroxy-8-methyl-1,2,3,7,8,8a-hexahydro-6H-3a,7-methanoazulen-6-one

上游原料

顺-4-己烯-1-醇 (Z)-己-4-烯醛 (Z)-1-(2-methoxyphenyl)hex-4-en-1-ol (Z)-tert-butyl((1-(2-methoxyphenyl)hex-4-en-1-yl)oxy)dimethylsilane (3R,3aR,6S,7R,8R,8aS)-3-((tert-butyldimethylsilyl)oxy)-6-hydroxy-8-methyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulen-9-one

下游产品

(3aR,5S,5aS,8S,8aS,9aR)-8-羟基-8a-(羟基甲基)-5-甲基-1-亚甲基-4,5,5a,6,7,8,9,9a-八氢-3aH-薁并[7,6-D]呋喃-2-酮 (3aR,4aS,7aS,8S,9aR)-4a-((benzyloxy)methyl)-8-methyldecahydroazuleno[6,5-b]furan-2,5-dione (3S,3aR,5S,6S,7S,8S,8aR,9S)-3-((tert-butyldimethylsilyl)oxy)-6-hydroxy-5-(2-hydroxyethyl)-8-methyloctahydro-1H-3a,7-methanoazulen-9-yl benzoate