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1,6-脱水-β-D-葡萄糖-2,3,4-三邻醋酸

1,6-脱水-β-D-葡萄糖-2,3,4-三邻醋酸

CAS号：13242-55-2

英文名：1,6-Anhydro-beta-D-glucose-2,3,4-tri-O-acetate

分子式

C12H16O8

熔点

111-112ºC

密度

1.34 g/cm3

分子量

288.251

沸点

392ºC at 760 mmHg

溶解度

信号词

危险品标志

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化合物简介

1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.

基本信息

中文名称

1,6-脱水-β-D-葡萄糖-2,3,4-三邻醋酸

英文名称

1,6-Anhydro-beta-D-glucose-2,3,4-tri-O-acetate

中文别名

2,3,4-三-O-乙酰-1,6-脱水-Β-D-葡萄糖

英文别名

1,6-ANHYDRO-β-D-GLUCOSE-2,3,4-TRI-O-ACETATE

CAS号

13242-55-2

分子式

C12H16O8

分子量

288.251

精确质量

288.085

PSA

97.36

LOGP

-0.4634

编号系统

EINECS号

236-222-1

物化性质

外观与性状

白色粉末

密度

1.34 g/cm3

沸点

392ºC at 760 mmHg

熔点

111-112ºC

闪点

147.3ºC

折射率

1.494

蒸汽压

0mmHg at 25°C

安全信息

安全说明

S24/25; S36; S26

危险类别码

R20/21/22

海关编码

2932999099

危险品标志

Xn

合成路线

共找到7条合成路线 >

(2R,3R,4S,5R,6S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate

(2R,3R,4S,5R,6S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate

1,6-脱水-β-D-葡萄糖-2,3,4-三邻醋酸

1,6-脱水-β-D-葡萄糖-2,3,4-三邻醋酸

上游原料

共找到33个上游原料 >

pentachlorophenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

pentachlorophenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

二丙酮-D-葡萄糖

二丙酮-D-葡萄糖

Tetramethylammonium methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 3-sulfate

Tetramethylammonium methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 3-sulfate

1,2,3,4-O-四乙酰基-6-O-三苯甲基-beta-D-吡喃葡萄糖

1,2,3,4-O-四乙酰基-6-O-三苯甲基-beta-D-吡喃葡萄糖

1,2,3,4,‐tetra‐O‐acetyl‐6‐tosyl‐6‐deoxy‐D‐glucopyranose

1,2,3,4,‐tetra‐O‐acetyl‐6‐tosyl‐6‐deoxy‐D‐glucopyranose

Tri-O-nitro-1,6-anhydro-β-D-glucopyranose

Tri-O-nitro-1,6-anhydro-β-D-glucopyranose

下游产品

共找到7个下游商品 >

1,6-anhydro-4-O-acetyl-β-D-glucopyranose

1,6-anhydro-4-O-acetyl-β-D-glucopyranose

1,6-anhydro-3-O-acetyl-β-D-glucopyranose

1,6-anhydro-3-O-acetyl-β-D-glucopyranose

β-D-葡萄糖五乙酸酯

β-D-葡萄糖五乙酸酯

1,6-脱水-2,4-O-苯基-Β-D-吡喃葡萄糖

1,6-脱水-2,4-O-苯基-Β-D-吡喃葡萄糖

1,6-脱水-β-D-葡萄糖

1,6-脱水-β-D-葡萄糖

上游原料

pentachlorophenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 二丙酮-D-葡萄糖 Tetramethylammonium methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 3-sulfate 1,2,3,4-O-四乙酰基-6-O-三苯甲基-beta-D-吡喃葡萄糖 1,2,3,4,‐tetra‐O‐acetyl‐6‐tosyl‐6‐deoxy‐D‐glucopyranose Tri-O-nitro-1,6-anhydro-β-D-glucopyranose 2,4,6-tri-O-acetyl-3-O-phenoxyacetyl-α-D-glucopyranosyl bromide 1,2,5,6-di-O-isopropylidene-3-O-phenoxyacetyl-α-D-glucofuranose 1,6-脱水-β-D-葡萄糖 1,2,3,4-二-O-异亚丙基-ALPHA-D-岩藻吡喃糖 2,3,4-Tri-O-acetyl-6-O-p-toluenesulfonyl-β-D-glucopyranose 对硝基甲苯 1,2,3,4-四-O-乙酰基-β-D-葡萄吡喃糖 1,2-O-exo-cyanoethylidene-4,6-di-O-acetyl-3-O-phenoxyacetyl-α-D-glucopyranose 1,6-脱水-2-脱氧-2-碘-D-吡喃葡萄糖 (3R,4S,5R,6R)-6-(((tert-butyldimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate 1,2,4,6-tetra-O-acetyl-3-O-phenoxyacetyl-D-glucopyranose α-D(+)-五乙酰葡萄糖 Methyl-4,6-O-benzyliden-α-D-glucopyranosid-2,3-cycl.-sulfat 乙酰氯 methyl-4,6-O-benzylidene-α-D-mannopyranoside 1,2-O-exo-cyanoethylidene-4,6-di-O-acetyl-α-D-glucopyranose 醋酸乙烯酯乙酸酐 1,2-O-exo-cyanoethylidene-4,6-di-O-acetyl-3-O-trityl-α-D-glucopyranose 6-O-p-toluenesulfonyl-D-mannopyranose 乙酰溴-α-D-葡萄糖 methyl 1,2,4-tri-O-acetyl-6-O-benzyl-β-D-glucopyranoside β-D-glucopyranosyl fluoride D-葡萄糖 pentabromophenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (2R,3R,4S,5R,6S)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-6-(4-methoxyphenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate

下游产品

1,6-anhydro-4-O-acetyl-β-D-glucopyranose 1,6-anhydro-3-O-acetyl-β-D-glucopyranose β-D-葡萄糖五乙酸酯 1,6-脱水-2,4-O-苯基-Β-D-吡喃葡萄糖 1,6-脱水-β-D-葡萄糖