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α-D(+)-五乙酰葡萄糖

α-D(+)-五乙酰葡萄糖

CAS号：604-68-2

英文名：α-D(+)-Glucose pentaacetate

分子式

C16H22O11

熔点

109-113ºC

密度

1.3 g/cm3

分子量

390.339

沸点

452ºC

溶解度

信号词

危险品标志

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化合物简介

D-Glucose pentaacetate was reported to stimulate insulin release in rat pancreatic islets. Only α-D-glucose pentaacetate caused an immediate increase in insulin output. The β-anomer of D-glucose pentaacetate first transiently inhibited insulin release, this initial effect being followed by a secondary rise in secretory rate.

基本信息

中文名称

α-D(+)-五乙酰葡萄糖

英文名称

α-D(+)-Glucose pentaacetate

中文别名

1,2,3,4,6-五乙酰-α-D-吡喃葡萄糖酯、葡萄糖五乙酸酯、α-D-葡萄糖五乙酸酯、1,2,3,4,6-五-O-乙酰-α-D-吡喃葡萄糖、1,2,3,4,6-alpha-D-葡萄糖五乙酸酯、α-葡萄糖五乙酸酯、a-D-葡糖五乙酸酯、五-O-乙酰-α-D-吡喃葡萄糖、α-五乙酰葡萄糖

英文别名

α-D-Glucopyranose, pentaacetate、[(2R,3R,4S,5R,6R)-3,4,5,6-tetraacetyloxyoxan-2-yl]methyl acetate

CAS号

604-68-2

分子式

C16H22O11

分子量

390.339

精确质量

390.116

PSA

140.73

LOGP

-0.3674

编号系统

MDL号

MFCD00064071

物化性质

外观与性状

无气味的白色粉末

密度

1.3 g/cm3

沸点

452ºC

熔点

109-113ºC

折射率

1.482

稳定性

Stable under normal temperatures and pressures.

储存条件

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

安全信息

安全说明

S24/25

危险类别码

R21

WGK Germany

3

海关编码

29400000

危险品标志

Xn; Xi

生产方法及用途

生产方法

一、生产方法简介由葡萄糖经乙酰化反应制备。

用途

二、用途是合成糖苷及寡糖的重要中间体。

合成路线

共找到32条合成路线 >

对甲酚

β-D-葡萄糖五乙酸酯

β-D-葡萄糖五乙酸酯

α-D(+)-五乙酰葡萄糖

α-D(+)-五乙酰葡萄糖

4-methylphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (en).β.-D-Glucopyranoside, 4-methylphenyl, tetraacetate (en)

4-methylphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (en).β.-D-Glucopyranoside, 4-methylphenyl, tetraacetate (en)

4-methylphenyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside

4-methylphenyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside

上游原料

共找到69个上游原料 >

葡萄糖

间甲酚

2,3,4,6-四-o-乙酰基-alpha-d-吡喃葡萄糖苷甲酯

2,3,4,6-四-o-乙酰基-alpha-d-吡喃葡萄糖苷甲酯

2-氯乙基β-D-果吡喃糖苷

2-氯乙基β-D-果吡喃糖苷

2-氯乙醇

2,3,4,6-tetra-O-acetyl-1-ethylsulfanyl-β-D-glucopyranoside

2,3,4,6-tetra-O-acetyl-1-ethylsulfanyl-β-D-glucopyranoside

下游产品

共找到34个下游商品 >

N-[3-[4-(3-氨基丙基氨基)丁基氨基]丙基]乙酰胺

N-[3-[4-(3-氨基丙基氨基)丁基氨基]丙基]乙酰胺

4-甲基-7-((2,3,4,6-四-O-乙酰基-beta-D-吡喃葡萄糖基)氧基)-2H-1-苯并吡喃-2-酮

4-甲基-7-((2,3,4,6-四-O-乙酰基-beta-D-吡喃葡萄糖基)氧基)-2H-1-苯并吡喃-2-酮

4-methylphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (en).β.-D-Glucopyranoside, 4-methylphenyl, tetraacetate (en)

4-methylphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (en).β.-D-Glucopyranoside, 4-methylphenyl, tetraacetate (en)

1-Fluoro-1-deoxy-α-D-glucose

1-Fluoro-1-deoxy-α-D-glucose

勒胖停

己基-Β-D-硫代吡喃葡萄糖苷

己基-Β-D-硫代吡喃葡萄糖苷

上游原料

葡萄糖间甲酚 2,3,4,6-四-o-乙酰基-alpha-d-吡喃葡萄糖苷甲酯 2-氯乙基β-D-果吡喃糖苷 2-氯乙醇 2,3,4,6-tetra-O-acetyl-1-ethylsulfanyl-β-D-glucopyranoside 葡萄糖 1-O-(2-trimethylsilylethyl)-β-D-glucopyranoside (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((5,5-dimethyl-2-sulfido-1,3,2-dioxaphosphinan-2-yl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 乙酰氯醋酸乙烯酯乙酸酐 β-D-葡萄糖五乙酸酯乙酰溴-α-D-葡萄糖 2-(trimethylsilyl)ethyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside D-葡萄糖 2,3,4,6-四-O-乙酰-β-D-吡喃葡萄糖硫酚对硝基苯酚甲基α-D-吡喃葡萄糖苷对甲酚莨菪亭 2-巯基甲苯 (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((4-methoxyphenyl)thio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 3,4,6-Tri-O-acetyl-1,2-O-(1-<4-(4-biphenylyl)butyryloxy>ethyliden)-α-D-glucopyranose 甲基β-D-吡喃葡萄糖苷半水合物 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-1-deoxy-α-D-glucoside 2,3,4,6-四邻苄基-alpha-d-吡喃葡萄糖 2,3,4,6-tetra-O-acetyl-1-O-(2-trimethylsilylethyl)-β-D-glucopyranoside 三-O-乙酰基-D- 葡萄烯糖乙酸异丙烯酯 Benzyl-2,3-O-isopropyliden-5-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-β-D-ribofuranosid 醋酸白砂糖 1-叠氮-1-脱氧-β-D-吡喃葡萄糖苷四乙酸酯 (E)-4-(2',3',4',6'-Tetra-O-acetyl-β-D-glucopyranosyloxy)but-3-en-2-one 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 1-O-(2-trimethylsilylethyl)-β-D-glucopyranoside 甲醇 acetic-p-nitrobenzoic anhydride Ac4-β-D-Man-NH2 乙烯酮 acetyl 3,4,6-tri-O-acetyl-α-D-glucopyranose 2-(trimethylsilyl)ethyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside

下游产品

N-[3-[4-(3-氨基丙基氨基)丁基氨基]丙基]乙酰胺 4-甲基-7-((2,3,4,6-四-O-乙酰基-beta-D-吡喃葡萄糖基)氧基)-2H-1-苯并吡喃-2-酮 4-methylphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (en).β.-D-Glucopyranoside, 4-methylphenyl, tetraacetate (en) 1-Fluoro-1-deoxy-α-D-glucose 勒胖停己基-Β-D-硫代吡喃葡萄糖苷十烷基-β-D-硫代吡喃葡萄糖苷 1,2,3,4-四-O-乙酰基-β-D-葡萄吡喃糖正壬基 beta-D-硫代吡喃葡萄糖苷 2-硝基苯基2,3,4,6-四-O-乙酰基-alpha-D-吡喃葡萄糖苷三-O-乙酰基-D- 葡萄烯糖 Methyl tetra-O-methyl-.β.-D-glucoside 1,6-脱水-2-脱氧-2-碘-D-吡喃葡萄糖甲基2,3,4,6-四-O-乙酰基-1-硫代-β-D-吡喃葡萄糖苷 1-叠氮-1-脱氧-β-D-吡喃葡萄糖苷四乙酸酯 2,3,4,5-tetramethoxy-6-(methoxymethyl)tetrahydro-2H-pyran 2-硝基苯基2,3,4,6-四-O-乙酰基-beta-D-吡喃葡萄糖苷苯基-2,3,4,6-四-O-乙酰-β-D-葡萄糖苷苯基 2,3,4,5-四-O-乙酰基-alpha-D-吡喃葡萄糖苷乙酰溴-α-D-葡萄糖 1,6-脱水-2-叠氮-2-脱氧-3,4-双-O-苄基-beta-D-吡喃葡萄糖 2,3,4,6-四邻乙酰基-alpha-d-吡喃葡萄糖三氯乙酰胺 1,2,3,6-四-o-乙酰基-alpha-d-吡喃葡萄糖 2,3,4,6-四-O-乙酰-β-D-吡喃葡萄糖 1,6-脱水-β-D-葡萄糖-2,3,4-三邻醋酸 4-methylphenyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside 辛基 2,3,4,6-四-O-乙酰基-beta-D-硫代吡喃葡萄糖苷辛基-beta-D-硫代吡喃葡萄糖苷 N-[2-[[2-[(2-氨基乙基)氨基]乙基]氨基]乙基]-乙酰胺 acetyl 3,4,6-tri-O-acetyl-α-D-glucopyranose 庚基-Β-D-硫代吡喃葡萄糖苷 4-甲基伞形酮酰-Β-D-吡喃葡糖酸苷 1-硫代-b-D-葡萄糖四乙酸酯