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三(二甲胺基)膦

三(二甲胺基)膦

CAS号：1608-26-0

英文名：Hexamethylphosphorous triamide

分子式

C6H18N3P

熔点

-44 °C

密度

0.898g/mLat 25°C(lit.)

分子量

163.201

沸点

48-50°C12mm Hg(lit.)

溶解度

REACTS

信号词

危险品标志

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化合物简介

A compound widely used in industry, with applications such as being a flame retardant for building materials to a phosphorylating agent in synthetic chemistry. It is a classified carcinogen.

基本信息

中文名称

三(二甲胺基)膦

英文名称

Hexamethylphosphorous triamide

中文别名

三(二甲氨基)膦、六甲基亚磷酰三胺

英文别名

Phosphorous triamide, hexamethyl-、N,N,N\',N\',N\'\',N\'\'-Hexamethylphosphinetriamine、(Me2N)3P HMPT、HMPT (may contain precipitate)、Tris(dimethylamino)phosphine、Hexamethylphosphorous Triamide (may contain precipitate)、Hexamethyltriaminophosphine、Tris(dimethylamino)phosphine (may contain precipitate)、Hexamethyltriamidophosphite、N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine

CAS号

1608-26-0

分子式

C6H18N3P

分子量

163.201

精确质量

163.124

PSA

23.31

LOGP

0.8981

编号系统

BRN号

906778

MDL号

MFCD00008301

PubChem号

24889847

物化性质

外观与性状

无色液体

密度

0.898g/mLat 25°C(lit.)

沸点

48-50°C12mm Hg(lit.)

熔点

-44 °C

闪点

73°F

折射率

n20/D 1.463(lit.)

水溶解性

REACTS

稳定性

Stable. Highly flammable - note low flash point. Incompatible with oxidizing agents.

储存条件

Store at RT.

蒸汽压

2.4mmHg at 25°C

安全信息

RTECS号

TH3390000

安全说明

S53-S45-S36/37/39-S26-S16

WGK Germany

3

危险类别码

R10; R36/37/38; R40

海关编码

29299000

危险品运输编码

UN 1993 3/PG 3

危险类别

3

包装等级

III

危险品标志

Xn

生产方法及用途

生产方法

将137.3g(1.0mol)三氯化磷溶于1.5L无水乙醚,搅拌,冷至1-5℃,通入过量的无水二甲胺气体,控制通气速度,使反应温度不超过15℃,通气毕,在氮氛中于室温放置过夜,滤除二甲胺盐酸盐,滤液减压蒸发回收乙醚,得152-154g,油状的六甲基亚磷酰三胺,收率94-95%。

用途

有机合成中间体。

合成路线

共找到96条合成路线 >

二甲基氯化磷胺

二甲基氯化磷胺

双(二甲基氨)氯膦

双(二甲基氨)氯膦

三(二甲胺基)膦

三(二甲胺基)膦

海关数据

共找到8个国家海关数据 >

国家/地区名称	海关编码	更新时间	操作
中国	2929909090	2019-03	查看
美国	2931909043	2019-03	查看
印度	29299090	2019-03	查看
欧盟	29299000	2019-03	查看
英国	2929900090	2019-03	查看
日本	292990000	2019-03	查看
韩国	2929909000	2019-03	查看
加拿大	2929900000	2019-03	查看

上游原料

共找到15个上游原料 >

phenyl tetramethylphosphorodiamidite

phenyl tetramethylphosphorodiamidite

亚氨基-三(二甲氨基)正膦

亚氨基-三(二甲氨基)正膦

二甲胺

chlorotris(dimethylamino)phosphonium chloride

chlorotris(dimethylamino)phosphonium chloride

1-(benzyloxy)-N,N,N',N'-tetramethylphosphinediamine

1-(benzyloxy)-N,N,N',N'-tetramethylphosphinediamine

二甲基氯化磷胺

二甲基氯化磷胺

下游产品

共找到101个下游商品 >

(E)-3-(N,N-dimethylamino)-prop-2-enamide

(E)-3-(N,N-dimethylamino)-prop-2-enamide

tris(dimethylamino)methylphosphonium tetraphenylborate

tris(dimethylamino)methylphosphonium tetraphenylborate

双苯酰草胺

双苯酰草胺

三甲基脲

5,12,19,26-tetraisopropyl-5H,12H,19H,26H-benzo[4,5][1,3,2]diazaphospholo[1,2-a]benzo[4,5][1,3,2]diazaphospholo[1,2-c]benzo[4,5][1,3,2]diazaphospholo[1,2-e]benzo[4,5][1,3,2]diazaphospholo[1,2-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine

5,12,19,26-tetraisopropyl-5H,12H,19H,26H-benzo[4,5][1,3,2]diazaphospholo[1,2-a]benzo[4,5][1,3,2]diazaphospholo[1,2-c]benzo[4,5][1,3,2]diazaphospholo[1,2-e]benzo[4,5][1,3,2]diazaphospholo[1,2-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine

tetrachlorobenzo[1,3,2]dioxaphosphol-2-yl-dimethylamine

tetrachlorobenzo[1,3,2]dioxaphosphol-2-yl-dimethylamine

上游原料

phenyl tetramethylphosphorodiamidite 亚氨基-三(二甲氨基)正膦二甲胺 chlorotris(dimethylamino)phosphonium chloride 1-(benzyloxy)-N,N,N',N'-tetramethylphosphinediamine 二甲基氯化磷胺 1,1-bis(dimethylamino)-N,N-dimethyl-N'-[4-(trifluoromethyl)phenyl]phosphinecarboximidamide tetrakis(dimethylamino)phosphonium iodide 1,1'-(naphthalene-1,7-diylbis(oxy))bis(N,N,N',N'-tetramethylphosphanediamine) 1,1'-(naphthalene-2,7-diylbis(oxy))bis(N,N,N',N'-tetramethylphosphanediamine) 双(二甲基氨)氯膦 1,1'-(naphthalene-1,3-diylbis(oxy))bis(N,N,N',N'-tetramethylphosphanediamine) N,N,N',N',N'',N''-hexamethylphosphorohydrazonic triamide naphthalene-1,5-diylbis(dimethylphosphoramidite) N,N-二甲基三甲基硅胺

下游产品

(E)-3-(N,N-dimethylamino)-prop-2-enamide tris(dimethylamino)methylphosphonium tetraphenylborate 双苯酰草胺三甲基脲 5,12,19,26-tetraisopropyl-5H,12H,19H,26H-benzo[4,5][1,3,2]diazaphospholo[1,2-a]benzo[4,5][1,3,2]diazaphospholo[1,2-c]benzo[4,5][1,3,2]diazaphospholo[1,2-e]benzo[4,5][1,3,2]diazaphospholo[1,2-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine tetrachlorobenzo[1,3,2]dioxaphosphol-2-yl-dimethylamine 二甲基氯化磷胺双(二甲基氨)氯膦 5H,12H,19H,26H-benzo[4,5][1,3,2]diazaphospholo[1,2-a]benzo[4,5][1,3,2]diazaphospholo[1,2-c]benzo[4,5][1,3,2]diazaphospholo[1,2-e]benzo[4,5][1,3,2]diazaphospholo[1,2-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine N,N-二甲基脲 1,6,11,16-tetrapropyloctahydro-1H,6H,11H,16H-tetrakis([1,3,2]diazaphospholo)[1,2-a:1',2'-c:1'',2''-e:1''',2'''-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine 5,12,19,26-tetrabenzyl-5H,12H,19H,26H-benzo[4,5][1,3,2]diazaphospholo[1,2-a]benzo[4,5][1,3,2]diazaphospholo[1,2-c]benzo[4,5][1,3,2]diazaphospholo[1,2-e]benzo[4,5][1,3,2]diazaphospholo[1,2-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine N,N-二甲基苯甲酰胺六甲基磷酰三胺二甲胺二氟一氯溴甲烷 N,N-dimethyl-1,3,2-benzodioxaphosphol-2-amine 1,2,3-benzazadiphosphole 亚磷酸三苄酯 N-二(二甲基氨基)硫代膦酰-N-甲基甲胺 2,5,8,11-Tetramethyl-octahydro-1,3a,4,6a,7,9a,10,12a-octaaza-3b,6b,9b,12b-tetraphospha-tetracyclopenta[a,c,e,g]cyclooctene 二苯乙酮基苯甲酸酯反-3-(二甲氨基)丙烯腈 N,N-dimethylundec-10-enamide 5,12,19,26-tetra-sec-butyl-5H,12H,19H,26H-benzo[4,5][1,3,2]diazaphospholo[1,2-a]benzo[4,5][1,3,2]diazaphospholo[1,2-c]benzo[4,5][1,3,2]diazaphospholo[1,2-e]benzo[4,5][1,3,2]diazaphospholo[1,2-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine 二溴二氟甲烷 2,8,9-三甲基-2,5,8,9-四氮杂-1-磷酰二环[3.3.3]十一烷 N-(4-甲基苯基)磺酰氨基甲酸乙酯非草隆菲醌 2-methoxyethyl benzoate 叔丁基亚氨基-三(二甲氨基)正膦 1,6,11,16-tetraisopropyloctahydro-1H,6H,11H,16H-tetrakis([1,3,2]diazaphospholo)[1,2-a:1',2'-c:1'',2''-e:1''',2'''-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine N,N-二甲基三甲基硅胺 5,12,19,26-tetrapropyl-5H,12H,19H,26H-benzo[4,5][1,3,2]diazaphospholo[1,2-a]benzo[4,5][1,3,2]diazaphospholo[1,2-c]benzo[4,5][1,3,2]diazaphospholo[1,2-e]benzo[4,5][1,3,2]diazaphospholo[1,2-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine 3-dimethylamino-2-(bis<dimethylamino>-phosphino)-2,3-dihydro<1,3>benzothiazolo<3,2-d><1,2,4,3>triazaphosphole N-[dimethylamino(propan-2-yloxy)phosphanyl]-N-methylmethanamine 5,12,19,26-tetraethyl-5H,12H,19H,26H-benzo[4,5][1,3,2]diazaphospholo[1,2-a]benzo[4,5][1,3,2]diazaphospholo[1,2-c]benzo[4,5][1,3,2]diazaphospholo[1,2-e]benzo[4,5][1,3,2]diazaphospholo[1,2-g][1,3,5,7,2,4,6,8]tetrazatetraphosphocine 安息香乙醚 1-(2-thienyl)-2,2,2-trichloroethyl tetramethyldiamidophosphite N,N-二甲基己酰胺 1,4,7,10-Tetramethyl-octahydro-1,3a,4,6a,7,9a,10,12a-octaaza-3b,6b,9b,12b-tetraphospha-tetracyclopenta[a,c,e,g]cyclooctene N,N,4,4,5,5-hexamethyl-1,3,2-dioxaphospholan-2-amine Brom-bis-dimethylamino-phosphan 1-(3-(dimethylamino)-7-methylbenzo[4,5]thiazolo[3,2-d][1,2,4,3]triazaphosphol-2(3H)-yl)-N,N,N',N'-tetramethylphosphinediamine