百科

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

CAS号：184964-71-4

英文名：(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

分子式：C21H28O6

分子量：376.443

合成路线

(R)-1-((3aR,5S,6R,6aR)-2,2,6-trimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diol

(R)-1-((3aR,5S,6R,6aR)-2,2,6-trimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diol

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

6-O-benzyl-3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-allofuranose

6-O-benzyl-3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-allofuranose

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

乙氧甲酰基亚甲基三苯基膦

乙氧甲酰基亚甲基三苯基膦

2-(benzyloxy)-1-((3aR,5S,6S,6aR)-2,2,6-trimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethanone

2-(benzyloxy)-1-((3aR,5S,6S,6aR)-2,2,6-trimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethanone

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

溴化苄

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

(1R,3S,4R,5R)-3-[(E/Z)-1-benzyloxymethyl-2-ethoxycarbonylethenyl]-4-methyl-7,7-dimethyl-2,6,8-trioxabicyclo[3.3.0]octane

上游原料

(R)-1-((3aR,5S,6R,6aR)-2,2,6-trimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diol 溴化苄 6-O-benzyl-3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-allofuranose 乙氧甲酰基亚甲基三苯基膦 2-(benzyloxy)-1-((3aR,5S,6S,6aR)-2,2,6-trimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethanone

下游产品

(3R,4s,5r)-4-羟基-5-[(1s)-1-羟基-2-甲基丙基]-3-甲基-2-吡咯烷酮-5-羧酸