百科

ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

CAS号：213740-16-0

英文名：ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

分子式：C27H38O3Si

分子量：438.674

合成路线

ethyl 2-(dichlorophosphoryl)butanoate

ethyl 2-(dichlorophosphoryl)butanoate

ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

(R)-4-Benzyl-3-[(R)-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyryl]-oxazolidin-2-one

(R)-4-Benzyl-3-[(R)-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyryl]-oxazolidin-2-one

ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

(S)-(-)-1'-(4-tert-butyldiphenylsilyloxy-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine

(S)-(-)-1'-(4-tert-butyldiphenylsilyloxy-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine

ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate

上游原料

ethyl 2-(dichlorophosphoryl)butanoate (R)-4-Benzyl-3-[(R)-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyryl]-oxazolidin-2-one (S)-(-)-1'-(4-tert-butyldiphenylsilyloxy-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine

下游产品

(3Z,5R)-(+)-3-bromomethyl-7-tert-butyldiphenylsilyloxy-5-methylhept-3-ene (2'R,6'R,8E,10E,14Z,16E,3S,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene (2'R,6'R,8E,10E,14Z,16E,3R,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene