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1,4,8,11-四氮杂环十四烷

1,4,8,11-四氮杂环十四烷

CAS号：295-37-4

英文名：1,4,8,11-tetraazacyclotetradecane

分子式

C10H24N4

熔点

184-186°C(lit.)

密度

0.861g/cm3

分子量

200.324

沸点

321.1ºC at 760mmHg

溶解度

信号词

Warning

危险品标志

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化合物简介

Cyclam (1,4,8,11-tetraazacyclotetradecane) is an organic compound with the formula (NHCH2CH2NHCH2CH2CH2)2. It is a white solid that is soluble in water. The compound is notable as a macrocyclic ligand, which binds strongly to many transition metal cations. The compound was first prepared by the reaction of 1,3-dibromopropane and ethylenediamine.

基本信息

中文名称

1,4,8,11-四氮杂环十四烷

英文名称

1,4,8,11-tetraazacyclotetradecane

中文别名

环拉胺、1,4,8,11-四氮环十四烷

英文别名

JM 1498、1,4,8,11-tetrazacyclotetradecane、14-crown-4N4、Cyclam、EINECS 206-039-1、1,4,8,11-Tetraazacyclotetradecane

CAS号

295-37-4

分子式

C10H24N4

分子量

200.324

精确质量

200.2

PSA

48.12

LOGP

0.4538

编号系统

MDL号

MFCD00005105

物化性质

外观与性状

白色松软的针状结晶粉末

密度

0.861g/cm3

沸点

321.1ºC at 760mmHg

熔点

184-186°C(lit.)

闪点

153ºC

蒸汽压

0.000305mmHg at 25°C

安全信息

RTECS号

XA5254800

安全说明

S26-S36

危险类别码

R36/37/38

WGK Germany

3

海关编码

2933990090

危险品标志

Xi

危险性防范说明

P261; P305 + P351 + P338

危险标志

GHS07

信号词

Warning

危险性描述

H315; H319; H335

生产方法及用途

用途

普乐沙福中间体。

合成路线

共找到39条合成路线 >

1,4,8,11-四[(4-甲基苯基)磺酰基]-1,4,8,11-四氮杂环十四烷

1,4,8,11-四[(4-甲基苯基)磺酰基]-1,4,8,11-四氮杂环十四烷

1,4,8,11-四氮杂环十四烷

1,4,8,11-四氮杂环十四烷

上游原料

共找到12个上游原料 >

1,3-二溴丙烷

1,3-二溴丙烷

(3a<sup>1</sup>s,5a<sup>1</sup>r)-3a<sup>1</sup>-phenyldecahydro-1H,6H-3a,5a,8a,10a-tetraazapyrene

(3a<sup>1</sup>s,5a<sup>1</sup>r)-3a<sup>1</sup>-phenyldecahydro-1H,6H-3a,5a,8a,10a-tetraazapyrene

tetra(trifluoromethylsulfonyl)-1,4,8,11-tetraazocyclodecane

tetra(trifluoromethylsulfonyl)-1,4,8,11-tetraazocyclodecane

N,N',N'',N'''-tetratosyl-1,10-diamino-4,7-diazadecane

N,N',N'',N'''-tetratosyl-1,10-diamino-4,7-diazadecane

(3a<sup>1</sup>r,9as)-9a-phenyloctahydro-1H,4H,7H-1,3a,6a,9-tetraazaphenalene

(3a<sup>1</sup>r,9as)-9a-phenyloctahydro-1H,4H,7H-1,3a,6a,9-tetraazaphenalene

N,N'-(ethane-1,2-diyl)bis(1,1,1-trifluoro-N-(3-((trifluoromethyl)sulfonamido)propyl)methanesulfonamide)

N,N'-(ethane-1,2-diyl)bis(1,1,1-trifluoro-N-(3-((trifluoromethyl)sulfonamido)propyl)methanesulfonamide)

下游产品

共找到29个下游商品 >

1,4,8,11-四(二乙氨甲酰基甲基)-1,4,8,11-四氮杂环十四烷

1,4,8,11-四(二乙氨甲酰基甲基)-1,4,8,11-四氮杂环十四烷

1,4,8,11-四(乙氧碳酰甲基)-1,4,8,11-四氮环十四烷

1,4,8,11-四(乙氧碳酰甲基)-1,4,8,11-四氮环十四烷

1,4,8,11-四甲基-1,4,8,11-四氮杂-环一十四烷

1,4,8,11-四甲基-1,4,8,11-四氮杂-环一十四烷

1,4,8,11-tetrapropyl-1,4,8,11-tetrazacyclotetradecane

1,4,8,11-tetrapropyl-1,4,8,11-tetrazacyclotetradecane

普乐沙福

1,11-N,N'-bis(p-toluenesulphonyl)-1,4,8,11-tetraazacyclotetradecane

1,11-N,N'-bis(p-toluenesulphonyl)-1,4,8,11-tetraazacyclotetradecane

上游原料

1,3-二溴丙烷 (3a<sup>1</sup>s,5a<sup>1</sup>r)-3a<sup>1</sup>-phenyldecahydro-1H,6H-3a,5a,8a,10a-tetraazapyrene tetra(trifluoromethylsulfonyl)-1,4,8,11-tetraazocyclodecane N,N',N'',N'''-tetratosyl-1,10-diamino-4,7-diazadecane (3a<sup>1</sup>r,9as)-9a-phenyloctahydro-1H,4H,7H-1,3a,6a,9-tetraazaphenalene 1,4,8,11-四[(4-甲基苯基)磺酰基]-1,4,8,11-四氮杂环十四烷 N,N'-双(2-氨乙基)-1,3-丙二胺 Glyoxal 1,2-双(3-氨丙基氨基)乙烷 1,4,8,11-Tetrakis(toluene-p-sulphonyl)-1,4,8,11-tetraazaundecane

下游产品

1,4,8,11-四(二乙氨甲酰基甲基)-1,4,8,11-四氮杂环十四烷 1,4,8,11-四(乙氧碳酰甲基)-1,4,8,11-四氮环十四烷 1,4,8,11-四甲基-1,4,8,11-四氮杂-环一十四烷 1,4,8,11-tetrapropyl-1,4,8,11-tetrazacyclotetradecane 普乐沙福 1,11-N,N'-bis(p-toluenesulphonyl)-1,4,8,11-tetraazacyclotetradecane 1,4,8-三(叔丁氧碳酰)-1,4,8,11-四氮杂环十四烷顺式-十氢-1H,6H-3α,5α,8α,10α-四氮杂芘 1,8-bis-(4-methylphenyl)sulfonyl-1,4,8,11-tetrazacyclotetradecane 1,4,8,11-四(氨甲酰基甲基)-1,4,8,11-四氮杂环十四烷 2,2',2'',2'''-(1,4,8,11-四氮杂环十四烷-1,4,8,11-四基)四乙酸四盐酸盐水合物 1,4,8,11-tetrabenzyl-1,4,8,11-tetrazacyclotetradecane 4,11-dibenzyl-1,4,8,11-tetrazabicyclo[6.6.2]hexadecane 1,5,8,12-tetrazabicyclo[10.2.2]hexadecane 1-[4,8,11-tri(propanoyl)-1,4,8,11-tetrazacyclotetradec-1-yl]propan-1-one 1-methyl-1,4,8,11-tetrazacyclotetradecane 1,4,8-tris(carboethoxymethyl)-1,4,8,11-tetraazacyclotetradecane 1-[(4-nitrophenyl)methyl]-1,4,8,11-tetrazacyclotetradecane 1-[4,8-bis(2,2,2-trifluoroacetyl)-1,4,8,11-tetrazacyclotetradec-1-yl]-2,2,2-trifluoroethanone 1,8-二甲基-1,4,8,11-四氮杂环十四烷 1-(pyridin-2-ylmethyl)-1,4,8,11-tetrazacyclotetradecane 2-[4,8,11-tris(2-hydroxyethyl)-1,4,8,11-tetrazacyclotetradec-1-yl]ethanol 3-[4,8,11-tris(2-cyanoethyl)-1,4,8,11-tetrazacyclotetradec-1-yl]propanenitrile 普乐沙福中间体-1 1-hexadecyl-1,4,8,11-tetrazacyclotetradecane 1,4,8,11-四氮环[9.3.1.1(4,8)]十六烷 1,8-联苄基-1,4,8,11-四氮环十四烷 triethoxy-[3-(1,4,8,11-tetrazacyclotetradec-1-yl)propyl]silane 1-苄基-1,4,8,11-四氮环十四烷