百科

冰片

CAS号：464-45-9

英文名：(-)-borneol

分子式

C10H18O

熔点

206-209°C

密度

0.992g/cm3

分子量

154.249

沸点

210°C(lit.)

溶解度

INSOLUBLE

信号词

危险品标志

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化合物简介

(-)-Borneol, is used in traditional Chinese medicine as moxa. It is a component of many essential oils, and can be also used as natural insect repellent.

基本信息

中文名称

冰片

英文名称

(-)-borneol

中文别名

龙脑、(1S)-(-)-冰片、(-)-莰醇、右旋龙脑、2-莰醇、2-茨醇、左旋龙脑、合成右旋龙脑、(-)-冰片

英文别名

L-BORNEOL、FEMA 2157、2-bornanol、Bornan-2-ol、l-2-Bornanol、endo-(1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol、2-Camphanol、Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, (1S-endo)-、L(-)-Borneol、(？)-Borneol、Linderol、bornel、(−)-Borneol、(-)-Borneol、ngaicamphor

CAS号

464-45-9

分子式

C10H18O

分子量

154.249

精确质量

154.136

PSA

20.23

LOGP

2.1935

编号系统

EINECS号

204-712-4

MDL号

MFCD00074821

物化性质

外观与性状

白色粉末或大块

密度

0.992g/cm3

沸点

210°C(lit.)

熔点

206-209°C

闪点

150°F

折射率

-36 ° (C=5, EtOH)

水溶解性

INSOLUBLE

稳定性

Stable at room temperature in closed containers under normal storage and handling conditions.

储存条件

Flammables area

蒸汽密度

5.31 (vs air)

蒸汽压

0.0398mmHg at 25°C

安全信息

RTECS号

DT5095000

安全说明

S16-S36/37

危险类别码

R11

WGK Germany

2

海关编码

29061900

危险品运输编码

UN 1312 4.1/PG 3

危险类别

4.1

包装等级

III

危险品标志

F

生产方法及用途

生产方法

1.由樟脑经还原反应制取.
2.以松节油为原料制取。

合成路线

共找到16条合成路线 >

Bornyl-endo-OTMS

Bornyl-endo-OTMS

上游原料

共找到39个上游原料 >

3-bromo-2-(1-bornyloxy)tetrahydropyran

3-bromo-2-(1-bornyloxy)tetrahydropyran

2(S)-(1-bornyloxy)-3(R)-hydroxy-3,6-dihydro-2H-pyran

2(S)-(1-bornyloxy)-3(R)-hydroxy-3,6-dihydro-2H-pyran

2-(1-bornyloxy)-3,4-epoxytetrahydropyran

2-(1-bornyloxy)-3,4-epoxytetrahydropyran

(S)-芳樟醇

3-蒈烯

(-)-β-蒎烯

下游产品

共找到17个下游商品 >

2-苯基丙醛

(S)-(-)-2-phenylpropyl (R)-(-)-2-phenylpropanoate

(S)-(-)-2-phenylpropyl (R)-(-)-2-phenylpropanoate

(S)-2-氯-2-苯基乙酸

(S)-2-氯-2-苯基乙酸

(-)-莰烯

(-)-2-bornanyl 2-phenylpropanoate

(-)-2-bornanyl 2-phenylpropanoate

上游原料

3-bromo-2-(1-bornyloxy)tetrahydropyran 2(S)-(1-bornyloxy)-3(R)-hydroxy-3,6-dihydro-2H-pyran 2-(1-bornyloxy)-3,4-epoxytetrahydropyran (S)-芳樟醇 3-蒈烯 (-)-β-蒎烯龙脑 2-(1-bornyloxy)-5,6-dihydro-2H-pyran (+)-dithiocarbonic acid S-methyl ester-O-((1R)-bornyl ester) 硝基苯苯酐醋酸 2(S)-(1-bornyloxy)-3(R)-hydroxy-3,6-dihydro-2H-pyran 乙醇碘 (2S,3S,4S)-4-(phenylselanyl)-2-(((1S,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)oxy)tetrahydro-2H-pyran-3-ol 硫酸 L-bornyl p-toluenesulfonate 乙酸酐 2(S)-(1-bornyloxy)-3-oxo-3,6-dihydro-2H-pyran (-)-α-蒎烯二溴乙烷 [2(R)-(1-bornyloxy)-5,6-dihydro-2H-pyran-5(R)-yl]acetic acid (1S,2R,4S)-2-((4-methoxybenzyl)oxy)-1,7,7-trimethylbicyclo[2.2.1]heptane 左旋乙酸冰片酯 Bornyl-endo-OTMS [2(R)-(1-bornyloxy)-5,6-dihydro-2H-pyran-5(R)-yl]acetaldehyde 2(R)-(1-bornyloxy)-3(S)-(vinyloxy)-3,6-dihydro-2H-pyran (2(S)-(1-bornyloxy)-5,6-dihydro-2H-pyran-5(S)-yl)acetic acid 四氯化碳 2(S)-(1-bornyloxy)-3(S)-(vinyloxy)-3,6-dihydro-2H-pyran L(-)-樟脑 μ-disulfido-1,2-dithio-dicarbonic acid O,O'-dibornyl ester <2(S)-(1-bornyloxy)-5,6-dihydro-2H-pyran-5(R)-yl>acetic acid <2(S)-(1-bornyloxy)-5,6-dihydro-2H-pyran-5(S)-yl>acetaldehyde 樟脑 <2(S)-(1-bornyloxy)-5,6-dihydro-2H-pyran-5(R)-yl>acetaldehyde 2(S)-(1-bornyloxy)-3(R)-(vinyloxy)-3,6-dihydro-2H-pyran

下游产品

2-苯基丙醛 (S)-(-)-2-phenylpropyl (R)-(-)-2-phenylpropanoate (S)-2-氯-2-苯基乙酸莰烯 (-)-莰烯 (-)-2-bornanyl 2-phenylpropanoate (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) pentanoate 龙脑烯醛 2-Bornyl propionate 龙脑乙酸龙脑酯 L(-)-樟脑 1,7,7-三甲基双环[2.2.1]庚-2-基乳酸酯 (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) dodecanoate L-樟脑酸冰片基溴化物左旋-3-溴樟脑