百科

樟脑

CAS号：464-49-3

英文名：(R)-camphor

分子式

C10H16O

熔点

176-180ºC

密度

0.99 g/cm3

分子量

152.233

沸点

204ºC

溶解度

信号词

危险品标志

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化合物简介

樟脑，IUPAC名称1,7,7-三甲基二环[2.2.1]庚烷-2-酮，是一种萜类有机化合物，室温下为白色或透明的蜡状固体，可用于驱虫。樟脑提炼自樟树干中，树龄越老的的樟树所富含樟脑比例越多。提炼方法为将树干切成小块用水蒸馏，樟脑油受热后随着水蒸汽上升，在接触到预先放置在上方的陶缸冷却后便可形成樟脑。台湾早期北部山林多为原始樟树林，老樟树树龄千年以上者甚多，后日本政府在台湾大量砍伐樟脑输出，因此，台湾樟脑输出量曾达世界首位，有“樟脑王国”之称。现在世界上使用的樟脑丸多是由化学方式合成。

基本信息

中文名称

樟脑

英文名称

(R)-camphor

中文别名

D-(+)-樟脑、D(+)-樟脑、右旋樟脑、D-樟脑、(+)-樟脑、(1R)-(+)-樟脑、天然樟脑

英文别名

D-CAMPHOR、(+)-bornan-2-one、d-camphor、2-Bornanone,2-Camphanone,D-Camphor、(+)-CaMphor、(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one、2-Bornanone,2-Camphanone、D(+)-Camphor、2-Bornanone 2-Camphanone、(+)-Camphor,(1R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one、Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)-、D-(+)-Camphor

CAS号

464-49-3

分子式

C10H16O

分子量

152.233

精确质量

152.12

PSA

17.07

LOGP

2.4017

编号系统

UNII

N20HL7Q941

物化性质

外观与性状

白色晶体

密度

0.99 g/cm3

沸点

204ºC

熔点

176-180ºC

闪点

64ºC

稳定性

Stable. Incompatible with strong reducing agents, strong oxidizing agents, chlorinated solvents. Protect from direct sunlight.

储存条件

库房低温通风干燥,与氧化剂分开存放,防明火,高温

蒸汽压

0.225mmHg at 25°C

安全信息

安全说明

S16-S26-S37/39

危险类别码

R11; R36/37/38

海关编码

2914299000

危险品运输编码

UN 2717 4.1/PG 3

危险类别

4.1

包装等级

III

危险品标志

F; Xi

合成路线

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spiro[(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,5'-(phenyl)-1,4',2'-dioxazole]

spiro[(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,5'-(phenyl)-1,4',2'-dioxazole]

苯甲酰胺

上游原料

共找到95个上游原料 >

2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-ol

2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-ol

benzyl ((S)-1-oxo-1-((1R,2R,4R)-1,7,7-trimethyl-2-((trimethylsilyl)oxy)bicyclo[2.2.1]heptan-2-yl)pentan-3-yl)carbamate

benzyl ((S)-1-oxo-1-((1R,2R,4R)-1,7,7-trimethyl-2-((trimethylsilyl)oxy)bicyclo[2.2.1]heptan-2-yl)pentan-3-yl)carbamate

(1R)-2-endo-bromoacetyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

(1R)-2-endo-bromoacetyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

(+)-3-溴樟脑

(+)-3-溴樟脑

(1R)-2-endo-[(2R)-propyloctanoyl]-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

(1R)-2-endo-[(2R)-propyloctanoyl]-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

(1R)-1.7.7-trimethyl-2ξ-ethynyl-norbornanol-(2ξ)

(1R)-1.7.7-trimethyl-2ξ-ethynyl-norbornanol-(2ξ)

下游产品

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2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-ol

2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-ol

香芹酚

间甲酚

2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-amine

2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-amine

(+)-3-溴樟脑

(+)-3-溴樟脑

上游原料

2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-ol benzyl ((S)-1-oxo-1-((1R,2R,4R)-1,7,7-trimethyl-2-((trimethylsilyl)oxy)bicyclo[2.2.1]heptan-2-yl)pentan-3-yl)carbamate (1R)-2-endo-bromoacetyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol (+)-3-溴樟脑 (1R)-2-endo-[(2R)-propyloctanoyl]-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol (1R)-1.7.7-trimethyl-2ξ-ethynyl-norbornanol-(2ξ) spiro[(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,5'-(phenyl)-1,4',2'-dioxazole] 3-Bromo-d-camphor (R)-3-((tert-butyldimethylsilyl)oxy)-1-((1R,2R,4R)-2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)-4,4-dimethylpentan-1-one ((2S,3S)-3-Ethyl-oxiranyl)-((1R,2R,4R)-2-hydroxy-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-methanone (2R,3S)-2-bromo-3-hydroxy-1-((1R,2R,4R)-1,7,7-trimethyl-2-((trimethylsilyl)oxy)bicyclo[2.2.1]heptan-2-yl)pentan-1-one {(S)-3-((1R,2R,4R)-2-Hydroxy-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-3-oxo-1-[2-((2R,3R,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl]-propyl}-carbamic acid benzyl ester (1R)-樟脑肟乙醇 (1R)-2-endo-[(1R)-4-methylcyclohex-3-en-1-ylcarbonyl]-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol tert-butyl ((S)-1-oxo-1-(((S)-1-oxo-1-((1R,2R,4R)-1,7,7-trimethyl-2-((trimethylsilyl)oxy)bicyclo[2.2.1]heptan-2-yl)pentan-3-yl)amino)-3-phenylpropan-2-yl)carbamate enolacetate of camphor (S)-3-(4-chlorophenyl)-1-((1R,2R,4R)-2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)-4-nitrobutan-1-one (1R)-2-endo-propenoyl-1,7,7-trimethylbicyclo[2.2.1]-heptan-2-ol (-)-2exo-bromo-2endo-nitro-bornane 2-methylisoborneol 异龙脑 (1R)-2-endo-chloroacetyl-2-exo-trimethylsiloxy-1,7,7-trimethylbicyclo[2.2.1]heptane (1R)-2-endo-[(2S)-propyloctanoyl]-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol ((S)-1-{(S)-3-((1R,2R,4R)-2-Hydroxy-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-3-oxo-1-[2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl]-propylcarbamoyl}-2-phenyl-ethyl)-carbamic acid tert-butyl ester endo-2-acetylisoborneol camphor-4-nitrophenylhydrazone (R)-3-Hydroxy-1-((1R,2R,4R)-2-hydroxy-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-3-phenyl-propan-1-one (1R)-2-endo-[(1R,2R,4R)-bicyclo[2.2.1]hept-5-en-2-ylcarbonyl]-1,7,7-trimethylbicyclo[2.2.1]-heptan-2-ol 龙脑甲基锂 1,7,7-三甲基双环[2.2.1]庚烷-2-醇 {(S)-3-((1R,2R,4R)-2-Hydroxy-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-3-oxo-1-[2-((2R,3S,4R,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl]-propyl}-carbamic acid benzyl ester spiro[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3'-oxaziridine] {(S)-3-((1R,2R,4R)-2-Hydroxy-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-3-oxo-1-[2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl]-propyl}-carbamic acid benzyl ester (S)-1-((1R,2R,4R)-2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)-4-nitro-3-phenylbutan-1-one (1R,4R)-1-oxo-2-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-hydrazinium-1-olate (R)-3-hydroxy-1-((1R,2R,4R)-2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)-4-methylpentan-1-one 甲醇 (1R)-2-endo-(1-methoxy-1,2-propanodienyl)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol (4R)-1,7,7-三甲基双环[2.2.1]庚烷-2-亚胺 (+)-冰片 (1R)-(-)-硫代樟脑 (S)-3-amino-1-((1R,2R,4R)-2-hydroxy-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)-5-((2R,3S,4R,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)pentan-1-one

下游产品

2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-ol 乙醛香芹酚间甲酚 2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptan-4-amine (+)-3-溴樟脑 (1R)-(-)-樟脑醌 N-(4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl)formamide endo N-ethylbornylamine 六氯苯 bornane-2,6-dione 2-mercapto-p-cymene (2S)-(-)-2,2′-氧代二(八氢-7,8,8-三甲基-4,7-亚甲基苯并呋喃) 四氯化碳六氯乙烷 (1)-3-(Isopropyl)-6-methylcyclohex-2-en-1-one N-[(Z)-(4,7,7-trimethyl-3-bicyclo[2.2.1]heptanylidene)amino]pyridine-4-carboxamide P-伞花烃樟脑 (R)-(+)-莰胺 (1S)-(-)-樟脑内磺酰亚胺（1S）-10-樟脑磺酰胺 (+)-3,9-二溴茨酮异龙脑莰烯右旋樟脑-10-磺酰氯苯五甲酸 (-)-樟脑甲酸乙酯龙脑烯醛龙脑 [1R-(2-endo,3-exo)]-3-羟基-4,7,7-三甲基双环[2.2.1]庚烷-2-乙酸反式-(1R)-(+)-樟脑醌-3-肟冰片酮基蒎酸 D-樟脑酸 di-((1R)-bornyl)-disulfide 3,4-二甲基苯甲酸 3-(3-hydroxy-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl)-4,7,7-trimethylbicyclo[2.2.1]heptan-3-ol (1R,2s)-(+)-冰片胺盐酸盐 3-(全氟丁酰)-(+)-樟脑 D(+)-10-樟脑磺酸 (1R,4S)-3-hydroxyimino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 4-异丙基甲苯 exo N-ethylbornylamine 降樟腦三酸 1,2,3,5-四甲基苯 (+)-冰片 1,7,7-三甲基降冰片烷-2-硫醇