化合物简介
Phenyl-2-nitropropene is a chemical compound with the chemical formula is C9H9NO2. It can be produced by the reaction of benzaldehyde and nitroethane in the presence of a basic catalyst. In this reaction, the base deprotonates nitroethane to form a resonance stabilized anion. This anion nucleophilically adds to the aldehyde forming a beta nitro alcohol, which is subsequently dehydrated to yield the nitroalkene. This reaction is known as a nitroaldol reaction. Phenyl-2-nitropropene can be reduced in the presence of a catalyst to produce phenylacetone, which is a controlled precursor of methamphetamine. However, with lithium aluminium hydride it can simply be reduced to directly form amphetamine in moderate yields.
基本信息
中文名称
1-苯基-2-硝基丙烯
英文名称
1-Phenyl-2-nitropropene
中文别名
TRANS-BETA-甲基-BETA、2-甲基-2-硝基苯乙烯、2-硝基苯丙烯、2-硝基-1-苯基丙烯
英文别名
2-NITROPROP-1-ENYLBENZENE、2-NITRO-1-PHENYLPROPENE、1-Phenyl-2-nitro-1-propene、Benzene, (2-nitro-1-propenyl)-、2-nitro-1-phenyl-1-propene、NITROPROPENYLBENZENE
CAS号
705-60-2
分子式
C9H9NO2
分子量
163.173
精确质量
163.063
PSA
45.82
LOGP
2.8473
编号系统
MDL号
MFCD00014720
物化性质
外观与性状
橙色针状
密度
1.141 g/cm3
沸点
263ºC at 760 mmHg
熔点
63-65ºC
闪点
115.7ºC
折射率
1.586
安全信息
RTECS号
DA6495000
安全说明
S26; S36; S37/39
危险类别码
R36/37/38
WGK Germany
3
海关编码
2904209090
危险品标志
Xi
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