百科

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

CAS号：81225-23-2

英文名：p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

分子式：C49H53N4O11PSSi

分子量：965.09

合成路线

69077-57-2

3-p-nitrobenzyloxycarbonylaminothiopropionic acid

81225-23-2

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

81225-22-1

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-hydroxyacetate

81225-23-2

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

76855-69-1

4-乙酰氧基氮杂环丁酮

81225-23-2

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

81225-21-0

(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-<3-(p-nitrobenzyloxycarbonylamino)propionylthio>azetidin-2-one

81225-23-2

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

81225-41-4

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

81225-23-2

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

上游原料

3-p-nitrobenzyloxycarbonylaminothiopropionic acid (2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-hydroxyacetate 4-乙酰氧基氮杂环丁酮 (3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-<3-(p-nitrobenzyloxycarbonylamino)propionylthio>azetidin-2-one

下游产品

(5R,6S)-6-<(1R)-hydroxyethyl>-2-(2-aminoethyl)-2-penem-3-carboxylic acid p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-(2-p-nitrobenzyloxycarbonylaminoethyl)-2-penem-3-carboxylate p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-(4-p-nitrobenzyloxycarbonylaminobutan-1-yl)-2-penem-3-carboxylate p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(2-p-nitrobenzyloxycarbonylaminoethyl)-2-penem-3-carboxylate (5R,6S)-6-<(1R)-hydroxyethyl>-2-(3-aminopropan-1-yl)-2-penem-3-carboxylic acid p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-(3-p-nitrobenzyloxycarbonylaminopropan-1-yl)-2-penem-3-carboxylate (5R,6S)-6-<(1R)-hydroxyethyl>-2-(4-aminobutan-1-yl)-2-penem-3-carboxylic acid