百科

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

CAS号：81225-36-7

英文名：p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

分子式：C51H57N4O11PSSi

分子量：993.143

合成路线

81225-41-4

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

81225-36-7

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

76855-69-1

4-乙酰氧基氮杂环丁酮

81225-36-7

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

85579-48-2

5-(4-Nitro-benzyloxycarbonylamino)-pentanoic acid

81225-36-7

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

87154-01-6

5-(p-nitrobenzyloxycarbonylamino)pentanethioic S-acid

81225-36-7

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

81225-35-6

dl-p-nitrobenzyl 2-<(3R*,4S*)-3-<(1R*)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-hydroxyacetate

81225-36-7

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

105499-99-8

(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-<5-(p-nitrobenzyloxycarbonylamino)pentanoylthio>azetidin-2-one

81225-36-7

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

上游原料

5-(p-nitrobenzyloxycarbonylamino)pentanethioic S-acid dl-p-nitrobenzyl 2-<(3R*,4S*)-3-<(1R*)-(tert-butyldimethylsiloxy)ethyl>-4-(5-p-nitrobenzyloxycarbonylaminopentanoylthio)-2-oxoazetidin-1-yl>-2-hydroxyacetate (3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-<5-(p-nitrobenzyloxycarbonylamino)pentanoylthio>azetidin-2-one (2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester 5-(4-Nitro-benzyloxycarbonylamino)-pentanoic acid 4-乙酰氧基氮杂环丁酮

下游产品

p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(4-p-nitrobenzyloxycarbonylaminobutan-1-yl)-2-penem-3-carboxylate