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(+/-)-tirandamycin A

(+/-)-tirandamycin A

CAS号:85880-71-3
英文名:(+/-)-tirandamycin A
分子式:C22H27NO7
分子量:417.452
上游原料
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上游原料
<1R*-<1β,2α,4α,6β,7α,8β(2E,4E,6S*)>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienoic acid (3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane methyl <2E,4E,6S*<1R*-<1β,2α,4α,6β,7α,8β>>>-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)hepta-2,4-dienoate (1R*(1Z),2S*,3R*,4R*,5S*,6R*)-2,4-bis((tert-butyldimethylsilyl)oxy)-1-(3,3-dimethoxy-2-methyl-1-butenyl)-3,5-dimethyl-6-((trimethylsilyl)oxy)cyclohexan-1-ol (1R,2R,4S,6R,7S,8S)-8-((E)-(S)-4-Hydroxy-1,3-dimethyl-but-2-enyl)-1,2,7-trimethyl-3,9,10-trioxa-tricyclo[4.3.1.02,4]decan-5-one <4R*(1S*,2S*,4R*,6S*,7R*,8R*),2E>-2-methyl-4-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2-penten-1-yl acetate (1S,2S,3R,4R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-1-(4,5-dimethyl-furan-2-yl)-2,4-dimethyl-pentan-1-ol (2E*,4R*,5R*,6R*,7S*,9Z)-5,7-bis((tert-butyldimethylsilyl)oxy)-11,11-dimethoxy-2,4,6,10-tetramethyl-8-oxo-2,9-dodecadienyl acetate (2R*,3R*,4S*,5R*,7Z)-3,5-bis((tert-butyldimethylsilyl)oxy)-9,9-dimethoxy-2,4,8-trimethyl-6-oxo-7-decenal (1R*(1Z),2R*,3R*,4R*,5R*,6S*)-4,6-bis((tert-butyldimethylsilyl)oxy)-1-(3,3-dimethoxy-2-methyl-1-butenyl)-3,5-dimethylcyclohexan-1,2-diol (1R*,2S*,3S*,5R*,6R*)-tert-butyldimethyl<(3-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-5-hydroxy-4-oxo-1-cyclohexyl)oxy>silane methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α>>>-4-methyl-6-(1,4,8-trimethyl-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-en-3-yl)hepta-2,4-dionate (2E*,4R*,5R*,6R*,7S*,9Z)-5,7-bis((tert-butyldimethylsilyl)oxy)-11,11-dimethoxy-2,4,6,10-tetramethyl-8-oxo-2,9-dodecadienal ethyl N-(4-(diethoxyphosphinyl)-3-oxobutanoyl)-N-(2,4-dimethoxybenzyl)glycinate (7R,8s,9S)-tert-butyldimethyl<(7,9-dimethyl-1,4-dioxaspiro<4.5>decan-8-oyl)oxy>silane <1R*-<1β,2α,4α,6β,7α,8β(2E,4E,8S*)>>-N-(2,4-dimethoxybenzyl)-N-(2-ethoxy-2-oxoethyl)-3-oxo-6-methyl-8-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.02,4>dec-8-yl)-4,6-nonadienamide (1R,3S,4S,5R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-1,4,8-trimethyl-2,9-dioxa-bicyclo[3.3.1]non-7-en-6-one methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(1,4,8-trimethyl-6-((trimethylsilyl)oxy)-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate tirandamycic acid chloride methyl <2E,4E,6R*<1S*-<1α,3α,5α,6α,8β>>>-6-(6-hydroxy-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dionate (3R*,4R*,5R*,6S*)-<(3,5-dimethyl-4,6-bis((tert-butyldimethylsilyl)oxy)-1-cyclohexenyl)oxy>trimethylsilane methyl <2E,4E,6R*<1S*-<1α,3α,4β,5α,8β>>>-4-methyl-6-(6-oxo-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>non-6-en-3-yl)hepta-2,4-dionate (1R*,2R*,3S*,5R*,6S*)-tert-butyldimethyl<(3-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-5-((trimethylsilyl)oxy)-4-oxo-1-cyclohexyl)oxy>silane methyl <2E,4E,6R*(1S*-<1α,3α,4β,5α,6α,8β>)>-6-(6-((tert-butyldimethylsilyl)oxy)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonan-3-yl)-4-methylhepta-2,4-dienoate (2E*,4R*,5R*,6R*,7S*,9Z)-5,7-bis((tert-butyldimethylsilyl)oxy)-11,11-dimethoxy-2,4,6,10-tetramethyl-8-oxo-2,9-dodecadienol 3-(1-hydroxy-2-(diethoxyphosphinyl)ethylidene)-1-(2,4-dimethoxybenzyl)-2,4-pyrrolidinedion (7α,8α,9α)-7,9-dimethyl-1,4-dioxaspiro[4.5]decan-8-ol Acetic acid (2E,9Z)-(4S,5S,6S,7R)-5,7-dihydroxy-11,11-dimethoxy-2,4,6,10-tetramethyl-8-oxo-dodeca-2,9-dienyl ester (1s,2R,6S)-tert-butyldimethyl<(2,6-dimethyl-4-oxo-1-cyclohexyl)oxy>silane <4R*(1S*,5S*,6R*,7R*),2E>-2-methyl-4-(1,2,6-trimethyl-4-oxo-8,9-dioxabicyclo<3.3.1>non-2-en-7-yl)-2-penten-1-yl acetate (1R*,2S*,3S*,6R*)-tert-butyldimethyl<(2,6-dimethyl-3-hydroxy-4-oxocyclohexyl)oxy>silane (1R*,2R*,3S*,6R*)-tert-butyldimethyl<(3-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-4-oxo-1-cyclohexyl)oxy>silane